(p-cymene)RuLCl2 (L=1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene and 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) and related complexes as ring closing metathesis catalysts

被引：124

作者：

Jafarpour, L ^{[1
]}

Huang, JK ^{[1
]}

Stevens, ED ^{[1
]}

Nolan, SP ^{[1
]}

机构：

[1] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 18期

关键词：

D O I：

10.1021/om990357f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes of (eta(6)-arene)ruthenium bearing the carbene ligand 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes) and 1,3-bis(2, 6-diisopropylphenyl)-imidazol-2-ylidene (IPr) Ru(IMes)(Cl)(2)(eta(6)-arene), Ru-(IPr)(Cl)(2)(eta(6)-arene), and [Ru-C=C=CPh2(IMes)(Cl)(eta(6)-arene)]PF6 were prepared and found to be efficient catalyst precursors for ring closing olefin metathesis.

引用

页码：3760 / 3763

页数：4

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