Surface-Bound Gradients for Studies of Soft Materials Behavior

被引:81
作者
Genzer, Jan [1 ]
机构
[1] N Carolina State Univ, Dept Chem & Biomol Engn, Raleigh, NC 27695 USA
来源
ANNUAL REVIEW OF MATERIALS RESEARCH, VOL 42 | 2012年 / 42卷
基金
美国国家科学基金会;
关键词
self-assembly; grafted polymer; polymer brush; screening; directed motion; combinatorial materials science; high throughput; soft materials; SELF-ASSEMBLED MONOLAYERS; HIGH-THROUGHPUT CHARACTERIZATION; TRANSFER RADICAL POLYMERIZATION; NANOPARTICLE-DENSITY GRADIENTS; DIRECTED CELL-MIGRATION; CHEMICAL GRADIENTS; WETTABILITY GRADIENT; COMBINATORIAL APPROACH; PROTEIN GRADIENTS; THIN-FILMS;
D O I
10.1146/annurev-matsci-070511-155050
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We provide a succinct account of surface-bound gradient structures created from soft materials or those facilitating the study of soft materials behavior. We commence by classifying the chief attributes of gradient structures and offer a few examples of fabrication methods employed to generate such structures. We then illustrate the versatility of gradient assemblies in functioning as recording media for monitoring a physico-chemical process, facilitating fast screening of physico-chemical phenomena, and playing an important part in the design and fabrication of surface-anchored molecular and macromolecular engines for the directed transport of soft materials.
引用
收藏
页码:435 / 468
页数:34
相关论文
共 231 条
[1]   Self-assembly of block copolymer thin films [J].
Albert, Julie N. L. ;
Epps, Thomas H., III .
MATERIALS TODAY, 2010, 13 (06) :24-33
[2]   Generation of Monolayer Gradients in Surface Energy and Surface Chemistry for Block Copolymer Thin Film Studies [J].
Albert, Julie N. L. ;
Baney, Michael J. ;
Stafford, Christopher M. ;
Kelly, Jennifer Y. ;
Epps, Thomas H., III .
ACS NANO, 2009, 3 (12) :3977-3986
[3]   Induction of cell polarization and migration by a gradient of nanoscale variations in adhesive ligand spacing [J].
Arnold, Marco ;
Hirschfeld-Warneken, Vera C. ;
Lohmueller, Theobald ;
Heil, Patrick ;
Bluemmel, Jacques ;
Cavalcanti-Adam, Elisabetta A. ;
Lopez-Garcia, Monica ;
Walther, Paul ;
Kessler, Horst ;
Geiger, Benjamin ;
Spatz, Joachim P. .
NANO LETTERS, 2008, 8 (07) :2063-2069
[4]   Wetting-dewetting transition line in thin polymer films [J].
Ashley, KM ;
Raghavan, D ;
Douglas, JF ;
Karim, A .
LANGMUIR, 2005, 21 (21) :9518-9523
[5]   A flexible approach to the fabrication of chemical gradients [J].
Ballav, Nirmalya ;
Shaporenko, Andrey ;
Terfort, Andreas ;
Zharnikov, Michael .
ADVANCED MATERIALS, 2007, 19 (07) :998-+
[6]   Making Protein Patterns by Writing in a Protein-Repelling Matrix [J].
Ballav, Nirmalya ;
Thomas, Heidi ;
Winkler, Tobias ;
Terfort, Andreas ;
Zharnikov, Michael .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (32) :5833-5836
[7]  
Bauer E, 2010, LANGMUIR, V26, P8392
[8]   Combinatorial measurements of crystallization growth rate and morphology in thin films of isotactic polystyrene [J].
Beers, KL ;
Douglas, JF ;
Amis, EJ ;
Karim, A .
LANGMUIR, 2003, 19 (09) :3935-3940
[9]   Tuning the number density of nanoparticles by multivariant tailoring of attachment points on flat substrates [J].
Bhat, Rajendra R. ;
Genzer, Jan .
NANOTECHNOLOGY, 2007, 18 (02)
[10]   Surface-grafted polymer gradients: Formation, characterization, and applications [J].
Bhat, Rajendra R. ;
Tomlinson, Michael R. ;
Wu, Tao ;
Genzer, Jan .
SURFACE- INITIATED POLYMERIZATION II, 2006, 198 :51-124