Ruthenium complexes bearing bidentate Schiff base ligands as efficient catalysts for organic and polymer syntheses

被引：237

作者：

Drozdzak, R ^{[1
]}

Allaert, B ^{[1
]}

Ledoux, N ^{[1
]}

Dragutan, I ^{[1
]}

Dragutan, V ^{[1
]}

Verpoort, F ^{[1
]}

机构：

[1] Univ Ghent, Dept Inorgan & Phys Chem, Lab Organomet Chem & Catalysis, B-9000 Ghent, Belgium

来源：

COORDINATION CHEMISTRY REVIEWS | 2005年 / 249卷 / 24期

关键词：

Schiff base ruthenium complex; olefin metathesis; N-heterocyclic carbenes; Kharash addition; enol-ester synthesis; hybrid catalyst;

D O I：

10.1016/j.ccr.2005.05.003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A concise overview is given on mononuclear and dinuclear, bidentate Schiff base ruthenium complexes with different additional ligands and on their applications in various chemical transformations such as Kharasch addition, enol-ester synthesis, alkyne dimerization, olefin metathesis and atom transfer radical polymerization. These new ruthenium complexes, conveniently prepared from commonly available ruthenium compounds, are very stable, exhibit a good tolerance towards organic functionalities, air and moisture and display high activity and chemoselectivity in chemical transformations. Relevant features of coordination chemistry connected with the reaction mechanism and chemoselectivity are also fully described. Since the nature of Schiff bases can be changed in a variety of ways, appealing routes for designing and preparing novel ruthenium complexes can be foreseen in the future. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：3055 / 3074

页数：20

共 297 条

[61] Kharasch addition and vinylation reactions mediated by ruthenium(II) complexes bearing Schiff base ligands [J].

De Clercq, B ;

Verpoort, F .

CATALYSIS LETTERS, 2002, 83 (1-2) :9-13

[62] Activity of a new class of ruthenium based ring-closing metathesis and ring-opening metathesis polymerization catalysts coordinated with a 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene and a Schiff base ligand [J].

De Clercq, B ;

Verpoort, F .

TETRAHEDRON LETTERS, 2002, 43 (50) :9101-9104

[63] A new class of ruthenium complexes containing Schiff base ligands as promising catalysts for atom transfer radical polymerization and ring opening metathesis polymerization [J].

De Clercq, B ;

Verpoort, F .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 180 (1-2) :67-76

[64] A new heterogeneous hybrid ruthenium catalyst being an eco-friendly option for the production of polymers and organic intermediates [J].

De Clercq, B ;

Lefebvre, F ;

Verpoort, F .

NEW JOURNAL OF CHEMISTRY, 2002, 26 (09) :1201-1208

[65]

De Clercq B, 2002, ADV SYNTH CATAL, V344, P639, DOI 10.1002/1615-4169(200208)344:6/7<639::AID-ADSC639>3.0.CO

[66]

2-0

[67] Ring-closing metathesis, Kharasch addition and enol ester synthesis catalysed by a novel class of ruthenium(II) complexes [J].

De Clercq, B ;

Verpoort, F .

TETRAHEDRON LETTERS, 2001, 42 (51) :8959-8963

[68] Monitoring of the polymerization of norbornene by in-line fiber-optic near IR-FT Raman [J].

De Clercq, B ;

Smellinckx, T ;

Hugelier, C ;

Maes, N ;

Verpoort, F .

APPLIED SPECTROSCOPY, 2001, 55 (11) :1564-1567

[69] Immobilization of multifunctional Schiff base containing ruthenium complexes on MCM-41 [J].

De Clercq, B ;

Lefebvre, F ;

Verpoort, F .

APPLIED CATALYSIS A-GENERAL, 2003, 247 (02) :345-364

[70] Ruthenium catalysed redox transformation of cinnamaldehyde to 3-phenylpropionic acid and methyl ester. [J].

de Vries, JG ;

Roelfes, G ;

Green, R .

TETRAHEDRON LETTERS, 1998, 39 (45) :8329-8332

← 2 3 4 5 6 7 8 9 10 11 →