Self-tuning MOCVD approach to the growth of very smooth La1-xPbxMnO3 thin films

被引:2
作者
Bosak, AA [1 ]
Samoilenkov, SV [1 ]
Gorbenko, OY [1 ]
Botev, AN [1 ]
Kaul, AR [1 ]
机构
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia
来源
INTERNATIONAL JOURNAL OF INORGANIC MATERIALS | 2001年 / 3卷 / 08期
关键词
MOCVD; perovskites; XRD; HREM; AFM;
D O I
10.1016/S1466-6049(01)00104-0
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new approach to the growth of complex oxide films free of any secondary phases using the volatile component was developed. The technique consists in a self-tuning of the oxide film composition during the growth due to the evaporation of the excess PbO. It was successfully used for the MOCVD growth of very smooth single phase La1-xPbxMnO3 (x=0.1-0.6) films on perovskite substrates and MgO at a deposition rate of similar to1 mum h(-1). High quality of the films was explained by the presence of quasi-liquid PbO surface layer activating the surface diffusion during the growth. (C) 2001 Published by Elsevier Science Ltd.
引用
收藏
页码:1097 / 1099
页数:3
相关论文
共 8 条
[1]   Properties and substitutional chemistry of layered lead cuprate superconductors [J].
Beales, TP .
JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (01) :1-12
[2]   Epitaxial BaTiO3 films grown by aerosol MOCVD [J].
Gorbenko, OY ;
Kaul, AR ;
Wahl, G .
CHEMICAL VAPOR DEPOSITION, 1997, 3 (04) :193-&
[3]   NEW PRINCIPLE OF FEEDING FOR FLASH EVAPORATION MOCVD DEVICES [J].
KAUL, AR ;
SELEZNEV, BV .
JOURNAL DE PHYSIQUE IV, 1993, 3 (C3) :375-378
[4]   Self-limiting process for the bismuth content in molecular beam epitaxial growth of Bi2Sr2CuOy thin films [J].
Migita, S ;
Kasai, Y ;
Ota, H ;
Sakai, S .
APPLIED PHYSICS LETTERS, 1997, 71 (25) :3712-3714
[5]   Volatile surfactant assisted MOCVD of oxide materials [J].
Molodyk, AA ;
Kaul, AR ;
Gorbenko, OY ;
Novojilov, MA ;
Korsakov, IE ;
Wahl, G .
JOURNAL DE PHYSIQUE IV, 1999, 9 (P8) :709-716
[6]  
PRESCHER K E, 1964, Z FAR ERZBERGBAU MET, V17, P28
[7]   Adsorption-controlled growth of Bi4Ti3O12 by reactive MBE [J].
Theis, CD ;
Yeh, J ;
Schlom, DG ;
Hawley, ME ;
Brown, GW ;
Jiang, JC ;
Pan, XQ .
APPLIED PHYSICS LETTERS, 1998, 72 (22) :2817-2819
[8]   Adsorption-controlled growth of PbTiO3 by reactive molecular beam epitaxy [J].
Theis, CD ;
Yeh, J ;
Schlom, DG ;
Hawley, ME ;
Brown, GW .
THIN SOLID FILMS, 1998, 325 (1-2) :107-114