Design of novel three-dimensional coordination polymers based on triangular trinuclear copper 1,2,4-triazolate units

被引：90

作者：

Zhai, Quan-Guo ^{[1
]}

Lu, Can-Zhong ^{[1
]}

Chen, Shu-Mei ^{[1
]}

Xu, Xin-Jiang ^{[1
]}

Yang, Wen-Bin ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2006年 / 6卷 / 06期

关键词：

D O I：

10.1021/cg0600142

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By controlling the molar ratios of copper dichloride dihydrate and 1,2,4-triazole (trz), we generated a series of novel three-dimensional coordination polymers constructed from mu(3)-oxo or mu(3)- Cl triangular copper units, exhibiting six-connected porous self-penetrating net, graphite layer, and inorganic-organic hybrid network structures, respectively.

引用

收藏

页码：1393 / 1398

页数：6

相关论文

共 47 条

[11] Organic-inorganic composite oxide phases:: one-dimensional molybdenum oxide chains entrained within a three-dimensional coordination complex cationic framework in [{Cu2(triazolate)2(H2O)2}Mo4O13] [J].

Hagrman, D ;

Zubieta, J .

CHEMICAL COMMUNICATIONS, 1998, (18) :2005-2006

[12] New approaches to the analysis of high connectivity materials:: Design frameworks based upon 44- and 63-subnet tectons [J].

Hill, RJ ;

Long, DL ;

Champness, NR ;

Hubberstey, P ;

Schröder, M .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :335-348

[13] Two mixed-valence copper(I,II) imidazolate coordination polymers: metal-valence tuning approach for new topological structures [J].

Huang, XC ;

Zhang, JP ;

Lin, YY ;

Yu, XL ;

Chen, XM .

CHEMICAL COMMUNICATIONS, 2004, (09) :1100-1101

[14] Highly interpenetrated metal-organic frameworks for hydrogen storage [J].

Kesanli, B ;

Cui, Y ;

Smith, MR ;

Bittner, EW ;

Bockrath, BC ;

Lin, WB .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (01) :72-75

[15] Supramolecular design of one-dimensional coordination polymers based on silver(I) complexes of aromatic nitrogen-donor ligands [J].

Khlobystov, AN ;

Blake, AJ ;

Champness, NR ;

Lemenovskii, DA ;

Majouga, AG ;

Zyk, NV ;

Schröder, M .

COORDINATION CHEMISTRY REVIEWS, 2001, 222 :155-192

[16] The coordination chemistry of 4-substituted 3,5-di(2-pyridyl)-4H-1,2,4-triazoles and related ligands [J].

Klingele, MH ;

Brooker, S .

COORDINATION CHEMISTRY REVIEWS, 2003, 241 (1-2) :119-132

[17] Self-assembly of discrete cyclic nanostructures mediated by transition metals [J].

Leininger, S ;

Olenyuk, B ;

Stang, PJ .

CHEMICAL REVIEWS, 2000, 100 (03) :853-907

[18] Low-dimensional hybrid copper halides with novel D6R CU6I6 cores [J].

Li, GH ;

Shi, Z ;

Liu, XM ;

Dai, ZM ;

Feng, SH .

INORGANIC CHEMISTRY, 2004, 43 (22) :6884-6886

[19] The first 'two-over/two-under' (2O/2U) 2D weave structure assembled from Hg-containing 1D coordination polymer chains [J].

Li, YH ;

Su, CY ;

Goforth, AM ;

Shimizu, KD ;

Gray, KD ;

Smith, MD ;

zur Loye, HC .

CHEMICAL COMMUNICATIONS, 2003, (14) :1630-1631

[20] Different oxidation states of copper(I, I/II, II) thiocyanate complexes containing 1,2,4-triazole as a bridging ligand:: Syntheses, crystal structures, and magnetic properties of 2-D polymer CuI(admtrz)SCN, linear trinuclear [CuI2CuII(admtrz)6(SCN)2](ClO4)2, and triangular trinuclear [CuII3(admtrz)4(SCN)3(μ3-OH)(H2O)](ClO4)2•H2O(admtrz = 4-amino-3,5-dimethyl-1,2,4-triazole) [J].

Liu, JC ;

Guo, GC ;

Huang, JS ;

You, XZ .

INORGANIC CHEMISTRY, 2003, 42 (01) :235-243

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