A terminal borylene ruthenium complex: From B-H activation to reversible hydrogen release

被引：101

作者：

Alcaraz, Gilles ^{[1
]}

Helmstedt, Ulrike ^{[2
]}

Clot, Eric ^{[2
]}

Vendier, Laure ^{[1
]}

Sabo-Etienne, Sylviane ^{[1
]}

机构：

[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse 04, France

[2] CNRS, UMR 53253, Inst Charles Gerhardt, ENSCM,UM1,UM2, F-34000 Montpellier, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 39期

关键词：

D O I：

10.1021/ja805164n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Starting from RuHCl(H-2)(PCy3)(2), a terminal ruthenium mesitylborylene complex was obtained via double B-H bond activation of mesitylborane and concomitant release of dihydrogen, such a process being remarkably reversible.

引用

页码：12878 / +

页数：3

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