Borylene transfer under thermal conditions for the synthesis of rhodium and iridium borylene complexes

被引：44

作者：

Braunschweig, Holger ^{[1
]}

Forster, Melanie ^{[1
]}

Kupfer, Thomas ^{[1
]}

Seeler, Fabian ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 32期

关键词：

boron; borylene complexes; iridium; rhodium;

D O I：

10.1002/anie.200801756

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Borylene transfer reactions to [(η5-C5R5)M(CO)2] (M = Rh, R = H; M = Ir, R = Me) using [(OC)5Mo=BN(SiMe3)2] as a borylene source proceed at room temperature and generate terminal rhodium and iridium borylene complexes (see scheme). Iridium complex 1 was characterized by X-ray crystallography. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5981 / 5983

页数：3

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