Finite element simulation of ion transfer reactions at a single micro-liquid | liquid interface supported on a thin polymer film

被引：38

作者：

Josserand, J

Morandini, J

Lee, HJ

Ferrigno, R

Girault, HH ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Lab Electrochim, CH-1015 Lausanne, Switzerland

[2] Simulog Grenoble, F-38330 Montbonnot St Martin, France

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1999年 / 468卷 / 01期

关键词：

ion transfer; cyclic voltammetry; simulation; finite element; ITIES;

D O I：

10.1016/S0022-0728(99)00052-2

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The electrochemical response of an ion transfer reaction at a polarised micro liquid I liquid interface has been studied by a finite element method. A new penalty method developed for this application has been first validated by comparison with experimental and analytical results obtained for a symmetric micro interface. Then, asymmetric geometries have been studied and the influence on the voltammetric response of parameters such as micro hole depth, interface position within the hole and diffusion coefficient ratio is investigated. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：42 / 52

页数：11

共 54 条

[1] Can cyclic voltammetry at microdisc electrodes be approximately described by one-dimensional diffusion?
Alden, JA
Hutchinson, F
Compton, RG
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (06) : 949 - 958
[2] DIFFUSIONAL MASS-TRANSPORT TO MICROBAND ELECTRODES OF PRACTICAL GEOMETRIES - A SIMULATION STUDY USING THE STRONGLY IMPLICIT PROCEDURE
ALDEN, JA
BOOTH, J
COMPTON, RG
DRYFE, RAW
SANDERS, GHW
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1995, 389 (1-2): : 45 - 54
[3] Amatore C., 1995, ELECTROCHEMISTRY ULT, P131
[4] SPACE VARIABLES WELL FITTED FOR THE STUDY OF STEADY-STATE AND NEAR-STEADY-STATE DIFFUSION AT A MICRODISK
AMATORE, CA
FOSSET, B
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1992, 328 (1-2): : 21 - 32
[5] MODELING OF AMPEROMETRIC BIOSENSORS BY A FINITE-VOLUME METHOD
BACHA, S
BERGEL, A
COMTAT, M
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1993, 359 (1-2): : 21 - 38
[6] An accurate microdisc simulation model for recessed microdisc electrodes
Bartlett, PN
Taylor, SL
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1998, 453 (1-2): : 49 - 60
[7] INVESTIGATION OF THE KINETICS OF ASSISTED POTASSIUM-ION TRANSFER BY DIBENZO-18-CROWN-6 AT THE MICRO-ITIES BY MEANS OF STEADY-STATE VOLTAMMETRY
BEATTIE, PD
DELAY, A
GIRAULT, HH
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1995, 380 (1-2) : 167 - 175
[8] INVESTIGATION OF THE KINETICS OF ION AND ASSISTED ION TRANSFER BY THE TECHNIQUE OF AC-IMPEDANCE OF THE MICRO-ITIES
BEATTIE, PD
DELAY, A
GIRAULT, HH
[J]. ELECTROCHIMICA ACTA, 1995, 40 (18) : 2961 - 2969
[9] Hydrodynamic voltammetry with channel microband electrodes: The simulation of voltammetric waveshapes
Bidwell, MJ
Alden, JA
Compton, RG
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1996, 417 (1-2): : 119 - 128
[10] A COMPARISON OF THE CHRONOAMPEROMETRIC RESPONSE AT INLAID AND RECESSED DISK MICROELECTRODES
BOND, AM
LUSCOMBE, D
OLDHAM, KB
ZOSKI, CG
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 249 (1-2): : 1 - 14

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