DNA-based hydrolytic kinetic resolution of epoxides

被引：43

作者：

Dijk, Ewold W. ^{[1
]}

Feringa, Ben L. ^{[1
]}

Roelfes, Gerard ^{[1
]}

机构：

[1] Univ Groningen, Stratingh Inst Chem, NL-9747 AG Groningen, Netherlands

来源：

TETRAHEDRON-ASYMMETRY | 2008年 / 19卷 / 20期

关键词：

D O I：

10.1016/j.tetasy.2008.10.004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

DNA-bound copper(H) complexes serve as catalysts for the hydrolytic kinetic resolution of 2-pyridyloxiranes in water. Selectivity factors of up to 2.7 were achieved, indicating a chirality transfer of DNA to epoxides via a coordinated metal ion. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：2374 / 2377

页数：4

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