Solution mediated phase transformation (RHO to SOD) in porous Co-imidazolate based zeolitic frameworks with high water stability

被引：82

作者：

Biswal, Bishnu P. ^{[1
]}

Panda, Tamas ^{[1
]}

Banerjee, Rahul ^{[1
]}

机构：

[1] CSIR Natl Chem Lab, Phys Mat Chem Div, Pune 411008, Maharashtra, India

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 97期

关键词：

CARBON-DIOXIDE CAPTURE; THERMAL-STABILITY; SEPARATION; METHANOL; ETHANOL; LIGAND; PORE;

D O I：

10.1039/c2cc36651g

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Here we report a highly porous, water stable Co based ZIF [CoNIm (RHO)] and its solution mediated phase transformation to a less porous and water unstable ZIF [CoNIm (SOD)]. CoNIm (RHO) has high Langmuir surface area [2087 m(2) g(-1)] as well as high water adsorption [200 cm(3) (STP) g(-1)] capacity.

引用

页码：11868 / 11870

页数：3

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