Synthesis of pure boron single-wall nanotubes

被引:294
作者
Ciuparu, D
Klie, RF
Zhu, YM
Pfefferle, L
机构
[1] Yale Univ, Dept Chem Engn, New Haven, CT 06520 USA
[2] Brookhaven Natl Lab, Ctr Funct Mat, Upton, NY 11973 USA
关键词
D O I
10.1021/jp049301b
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report here the first synthesis of pure boron single-wall nanotubes by reaction of BCl3 with H-2 over an Mg-MCM-41 catalyst with parallel, uniform diameter (36 +/- 1Angstrom) cylindrical pores. The composition of the tubular structures observed in TEM was confirmed by electron energy loss spectroscopy, and the tubular geometry was confirmed by the presence of the characteristic spectral features in the Raman breathing mode region.
引用
收藏
页码:3967 / 3969
页数:3
相关论文
共 21 条
  • [11] 2-Q
  • [12] Uniform-diameter single-walled carbon nanotubes catalytically grown in cobalt-incorporated MCM-41
    Ciuparu, D
    Chen, Y
    Lim, S
    Haller, GL
    Pfefferle, L
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (02) : 503 - 507
  • [13] Egerton R. F., 2011, ELECT ENERGY LOSS SP, DOI DOI 10.1007/978-1-4419-9583-4
  • [14] Proposed boron nanotubes
    Gindulyte, A
    Lipscomb, WN
    Massa, L
    [J]. INORGANIC CHEMISTRY, 1998, 37 (25) : 6544 - 6545
  • [15] Boron nanowires synthesized by laser ablation at high temperature
    Meng, XM
    Hu, JQ
    Jiang, Y
    Lee, CS
    Lee, ST
    [J]. CHEMICAL PHYSICS LETTERS, 2003, 370 (5-6) : 825 - 828
  • [16] Crystalline boron nanowires
    Otten, CJ
    Lourie, OR
    Yu, MF
    Cowley, JM
    Dyer, MJ
    Ruoff, RS
    Buhro, WE
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (17) : 4564 - 4565
  • [17] THE DEPOSITION CHARACTERISTICS AND THE STRUCTURAL NATURE OF THE DEPOSIT IN THE CHEMICAL VAPOR-DEPOSITION OF BORON
    PARK, CS
    YOO, JS
    CHUN, JS
    [J]. THIN SOLID FILMS, 1985, 131 (3-4) : 205 - 214
  • [18] Application of energy-filtering transmission electron microscopy to characterize amorphous boron nanowires
    Wang, YQ
    Duan, XF
    Cao, LM
    Li, G
    Wang, WK
    [J]. JOURNAL OF CRYSTAL GROWTH, 2002, 244 (01) : 123 - 128
  • [19] One-dimensional growth mechanism of amorphous boron nanowires
    Wang, YQ
    Duan, XF
    Cao, LM
    Wang, WK
    [J]. CHEMICAL PHYSICS LETTERS, 2002, 359 (3-4) : 273 - 277
  • [20] Microstructure and formation mechanism of titanium dioxide nanotubes
    Wang, YQ
    Hu, GQ
    Duan, XF
    Sun, HL
    Xue, QK
    [J]. CHEMICAL PHYSICS LETTERS, 2002, 365 (5-6) : 427 - 431