TiO2/Nafion film based electrochemiluminescence for detection of dissolved oxygen

被引:69
作者
Lin, Zhenyu
Liu, Yan
Chen, Guonan [1 ]
机构
[1] Fuzhou Univ, Key Lab Anal & Detect Technol Food Safety, Minist Educ, Fuzhou 350002, Fujian, Peoples R China
[2] Fuzhou Univ, Dept Chem, Fuzhou 350002, Fujian, Peoples R China
关键词
TiO2; nanocrystal; Electrochemiluminescence; Dissolved oxygen;
D O I
10.1016/j.elecom.2008.08.015
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
TiO2 nanocrystals had been modified on the surface of the glassy carbon electrode (GCE) with the help of Nafion. The electrochemiluminescence (ECL) behavior of the TiO2/Nafion GCE in aqueous solution was investigated. A possible mechanism about the ECL of TiO2 had also been proposed. The ECL intensity was linear with the dissolved oxygen concentration in the range of 0.30-10.00 mg/L with a detection limit of 0.12 mg/L. The developed method can be applied to detect the dissolved oxygen concentration or biochemical oxygen demand (BOD). (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:1629 / 1632
页数:4
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