Vapor-Phase Metalation by Atomic Layer Deposition in a Metal-Organic Framework

被引：838

作者：

Mondloch, Joseph E. ^{[1
]}

Bury, Wojciech ^{[1
,2
]}

Fairen-Jimenez, David ^{[1
]}

Kwon, Stephanie ^{[1
]}

DeMarco, Erica J. ^{[1
]}

Weston, Mitchell H. ^{[1
]}

Sarjeant, Amy A. ^{[1
]}

Nguyen, SonBinh T. ^{[1
]}

Stair, Peter C. ^{[1
]}

Snurr, Randall Q. ^{[1
]}

Farha, Omar K. ^{[1
]}

Hupp, Joseph T. ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem & Chem & Biol Engn, Evanston, IL 60208 USA

[2] Warsaw Univ Technol, Dept Chem, PL-00664 Warsaw, Poland

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 28期

关键词：

D O I：

10.1021/ja4050828

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-organic frameworks (MOFs) have received attention for a myriad of potential applications including catalysis, gas storage, and gas separation. Coordinatively unsaturated metal ions often enable key functional behavior of these materials. Most commonly, MOFs have been metalated from the condensed phase (i.e., from solution). Here we introduce a new synthetic strategy capable of metallating MOFs from the gas phase: atomic layer deposition (ALD). Key to enabling metalation by AID In MOFs (AIM) was the synthesis of NU-1000, a new, thermally stable, Zr-based MOP with spatially oriented -OH groups and large 1D mesopores and apertures.

引用

页码：10294 / 10297

页数：4

共 28 条

[1] High Propene/Propane Selectivity in Isostructural Metal-Organic Frameworks with High Densities of Open Metal Sites [J].

Bae, Youn-Sang ;

Lee, Chang Yeon ;

Kim, Ki Chul ;

Farha, Omar K. ;

Nickias, Peter ;

Hupp, Joseph T. ;

Nguyen, SonBinh T. ;

Snurr, Randall Q. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (08) :1857-1860

[2] Zr- and Hf-Based Metal-Organic Frameworks: Tracking Down the Polymorphism [J].

Bon, Volodymyr ;

Senkovska, Irena ;

Baburin, Igor A. ;

Kaskel, Stefan .

CRYSTAL GROWTH & DESIGN, 2013, 13 (03) :1231-1237

[3] A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability [J].

Cavka, Jasmina Hafizovic ;

Jakobsen, Soren ;

Olsbye, Unni ;

Guillou, Nathalie ;

Lamberti, Carlo ;

Bordiga, Silvia ;

Lillerud, Karl Petter .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (42) :13850-13851

[4] Postsynthetic Methods for the Functionalization of Metal-Organic Frameworks [J].

Cohen, Seth M. .

CHEMICAL REVIEWS, 2012, 112 (02) :970-1000

[5] Stereoselective construction of fluorinated indanone derivatives via a triple cascade Lewis acid-catalyzed reaction [J].

Cui, Han-Feng ;

Dong, Ke-Yan ;

Zhang, Guang-Wu ;

Wang, Lian ;

Ma, Jun-An .

CHEMICAL COMMUNICATIONS, 2007, (22) :2284-2286

[6] Hydrogen storage in microporous metal-organic frameworks with exposed metal sites [J].

Dinca, Mircea ;

Long, Jeffrey R. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (36) :6766-6779

[7]

Elam JW, 2012, ATOMIC LAYER DEPOSITION OF NANOSTRUCTURED MATERIALS, P227

[8] Conformal coating on ultrahigh-aspect-ratio nanopores of anodic alumina by atomic layer deposition [J].

Elam, JW ;

Routkevitch, D ;

Mardilovich, PP ;

George, SM .

CHEMISTRY OF MATERIALS, 2003, 15 (18) :3507-3517

[9] Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts [J].

Feng, Dawei ;

Gu, Zhi-Yuan ;

Li, Jian-Rong ;

Jiang, Hai-Long ;

Wei, Zhangwen ;

Zhou, Hong-Cai .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (41) :10307-10310

[10] Hybrid porous solids:: past, present, future [J].

Ferey, Gerard .

CHEMICAL SOCIETY REVIEWS, 2008, 37 (01) :191-214

← 1 2 3 →