Trinaphthylamines as Robust Organic Materials for Two-Photon-Induced Fluorescence

被引：81

作者：

Bordeau, Guillaume ^{[1
]}

Lartia, Remy ^{[1
]}

Metge, Germain ^{[2
]}

Fiorini-Debuisschert, Celine ^{[2
]}

Charra, Fabrice ^{[2
]}

Teulade-Fichou, Marie-Paule ^{[1
]}

机构：

[1] Ctr Univ, Inst Curie, CNRS UMR 176, F-91405 Orsay, France

[2] CEA Saclay, DSM DRECAM SPCSI, F-91191 Gif Sur Yvette, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 50期

关键词：

D O I：

10.1021/ja8055112

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of a novel pi-conjugated trinaphthylamines series is described. These original push-pull octupolar systems exhibit large two-photon action cross section (sigma(phi) up to 510 GM) increased by a factor of 2-3 as compared to their triphenylamines analogues. This substantial improvement of the two-photon absorption properties is attributed to the stronger donor character of the trinaphthyl core.

引用

页码：16836 / +

页数：3

共 25 条

[11] Two-photon absorption and broadband optical limiting with bis-donor stilbenes [J].

Ehrlich, JE ;

Wu, XL ;

Lee, IYS ;

Hu, ZY ;

Rockel, H ;

Marder, SR ;

Perry, JW .

OPTICS LETTERS, 1997, 22 (24) :1843-1845

[12]

Hagiya K, 2003, SYNTHESIS-STUTTGART, P823

[13] Two-photon excitation and optical spatial-profile reshaping via a nonlinear absorbing medium [J].

He, GS ;

Swiatkiewicz, J ;

Jiang, Y ;

Prasad, PN ;

Reinhardt, BA ;

Tan, LS ;

Kannan, R .

JOURNAL OF PHYSICAL CHEMISTRY A, 2000, 104 (20) :4805-4810

[14] Two-photon absorption cross-sections of reference dyes: A critical examination [J].

Jha, Prakash Chandra ;

Wang, Yanhua ;

Agren, Hans .

CHEMPHYSCHEM, 2008, 9 (01) :111-116

[15] Effects of (multi)branching of dipolar chromophores on photophysical properties and two-photon absorption [J].

Katan, C ;

Terenziani, F ;

Mongin, O ;

Werts, MHV ;

Porrès, L ;

Pons, T ;

Mertz, J ;

Tretiak, S ;

Blanchard-Desce, M .

JOURNAL OF PHYSICAL CHEMISTRY A, 2005, 109 (13) :3024-3037

[16] Synthetic strategies to derivatizable triphenylamines displaying high two-photon absorption [J].

Lartia, Remy ;

Allain, Clemence ;

Bordeau, Guillaume ;

Schmidt, Falk ;

Fiorini-Debuisschert, Celine ;

Charra, Fabrice ;

Teulade-Fichou, Marie-Paule .

JOURNAL OF ORGANIC CHEMISTRY, 2008, 73 (05) :1732-1744

[17] Two-photon absorption and nonlinear optical properties of octupolar molecules [J].

Lee, WH ;

Lee, H ;

Kim, JA ;

Choi, JH ;

Cho, MH ;

Jeon, SJ ;

Cho, BR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (43) :10658-10667

[18] Synthesis and characterization of water-soluble phenylene-vinylene-based singlet oxygen sensitizers for two-photon excitation [J].

Nielsen, CB ;

Johnsen, M ;

Arnbjerg, J ;

Pittelkow, M ;

McIlroy, SP ;

Ogilby, PR ;

Jorgensen, M .

JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (18) :7065-7079

[19] 3-DIMENSIONAL OPTICAL STORAGE MEMORY [J].

PARTHENOPOULOS, DA ;

RENTZEPIS, PM .

SCIENCE, 1989, 245 (4920) :843-845

[20] Enhanced two-photon absorption with novel octupolar propeller-shaped fluorophores derived from triphenylamine [J].

Porrés, L ;

Mongin, O ;

Katan, C ;

Charlot, M ;

Pons, T ;

Mertz, J ;

Blanchard-Desce, M .

ORGANIC LETTERS, 2004, 6 (01) :47-50

← 1 2 3 →