Synthesis, electrical characterization, and gas sensing properties of molybdenum oxide nanorods

被引:125
作者
Taurino, AM [1 ]
Forleo, A
Francioso, L
Siciliano, P
Stalder, M
Nesper, R
机构
[1] CNR, Inst Microelect & Microsyst, Dept Lecce, I-73100 Lecce, Italy
[2] Swiss Fed Inst Technol, Inorgan Chem Lab, ETH, CH-8092 Zurich, Switzerland
关键词
D O I
10.1063/1.2192571
中图分类号
O59 [应用物理学];
学科分类号
摘要
Gas sensors have been prepared by using single crystalline MoO3 nanorods. Structures 50-150 nm and up to 15 mu m in length were synthesized by template directed hydrothermal synthesis. Gas sensing tests showed responses to NO2 up to 740% and to NH3 up to 570%. Moreover, preliminary electrical characterizations were performed, as a function of temperature in 20-520 degrees C range temperature, by means of current-voltage measurements. I-V dependence studies show a linear increase in current at low voltage and a quadratic increase at higher voltages. A study of the current-temperature dependence shows that at high temperature current is thermally active and successively decreases that can be explained by taking in account a change of material morphology. (c) 2006 American Institute of Physics.
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页数:3
相关论文
共 18 条
[1]   Carbon monoxide response of molybdenum oxide thin films deposited by different techniques [J].
Comini, E ;
Faglia, G ;
Sberveglieri, G ;
Cantalini, C ;
Passacantando, M ;
Santucci, S ;
Li, Y ;
Wlodarski, W ;
Qu, W .
SENSORS AND ACTUATORS B-CHEMICAL, 2000, 68 (1-3) :168-174
[2]   Evaluation of the gap state distribution in a-Si:H by SCLC measurements [J].
Eray, A ;
Nobile, G .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2003, 76 (04) :521-528
[3]  
FRANCIOSO L, IN PRESS SCI CHINA B
[4]   Formation of alpha-molybdenum trioxide thin films to configure low-dimensional conductor [J].
Fukushima, C ;
Nagano, M ;
Sumita, T ;
Kubota, H ;
Nagata, M ;
Honda, Y ;
Oku, T ;
Imahori, J .
PHYSICA B, 1997, 239 (1-2) :56-58
[5]   MoO3, WO3 single and binary oxide prepared by sol-gel method for gas sensing applications [J].
Galatsis, K ;
Li, Y ;
Wlodarski, W ;
Cantalini, C ;
Passacantando, M ;
Santucci, S .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2003, 26 (1-3) :1097-1101
[6]   GaN nanorods coated with pure BN [J].
Han, WQ ;
Zettl, A .
APPLIED PHYSICS LETTERS, 2002, 81 (26) :5051-5053
[7]   A new preparation method for sputtered MoO3 multilayers for the application in gas sensors [J].
Imawan, C ;
Steffes, H ;
Solzbacher, F ;
Obermeier, E .
SENSORS AND ACTUATORS B-CHEMICAL, 2001, 78 (1-3) :119-125
[8]  
Lampert M. A., 1970, CURRENT INJECTION SO
[9]   Physical properties of sputtered molybdenum oxide thin films suitable for gas sensing applications [J].
Manno, D ;
Di Giulio, M ;
Serra, A ;
Siciliano, T ;
Micocci, G .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2002, 35 (03) :228-233
[10]   Gas-sensing properties of Ta-doped MoO3-x [J].
Merdrignac-Conanec, O ;
Moseley, PT .
ELECTROCHEMISTRY COMMUNICATIONS, 1999, 1 (02) :51-54