Transient FTIR spectroelectrochemical and stopped-flow detection of a mixed valence {Fe(I)-Fe(II)} bridging carbonyl intermediate with structural elements and spectroscopic characteristics of the di-iron sub-site of all-iron hydrogenase

被引：101

作者：

Razavet, M

Borg, SJ

George, SJ

Best, SP ^{[1
]}

Fairhurst, SA

Pickett, CJ

机构：

[1] Univ Melbourne, Sch Chem, Parkville, Vic 3010, Australia

[2] John Innes Ctr Plant Sci Res, Dept Biol Chem, Norwich NR4 7UH, Norfolk, England

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 07期

关键词：

D O I：

10.1039/b111613b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Iron( I) in biology?: one-electron oxidation of an {Fe(I)-Fe(I)} carbonyl cyanide precursor bearing a proximal thioether group leads to an {Fe(I)- Fe(II)} bridging carbonyl transient with spectral features similar to the di-iron sub-site of the CO inhibited paramagnetic centre of all-iron hydrogenase.

引用

页码：700 / 701

页数：2

共 22 条

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