Lithium oxides precipitation in nonaqueous Li-air batteries

被引:44
作者
Hou, Junbo [1 ]
Yang, Min [1 ]
Ellis, Michael W. [2 ]
Moore, Robert B. [3 ]
Yi, Baolian [4 ]
机构
[1] Virginia Tech, Inst Crit Technol & Appl Sci, Blacksburg, VA 24061 USA
[2] Virginia Tech, Dept Mech Engn, Blacksburg, VA 24061 USA
[3] Virginia Tech, Dept Chem, Blacksburg, VA 24061 USA
[4] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
关键词
PEM FUEL-CELL; OXYGEN REDUCTION; CARBON NANOTUBES; CATALYST LAYER; ENERGY DENSITY; LI-O-2; ELECTROLYTES; DISCHARGE; CATHODE; ELECTRODES;
D O I
10.1039/c2cp42768k
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Lithium-air/oxygen battery is a rising star in the field of electrochemical energy storage as a promising alternative to lithium ion batteries. Nevertheless, this alluring system is still at its infant stage, and the breakthrough of lithium-air batteries into the energy market is currently constrained by a combination of scientific and technical challenges. Targeting at the air electrode in nonaqueous lithium-air batteries, this review attempts to summarize the knowledge about the fundamentals related to lithium oxides precipitation, which has been one of the vital and attractive aspects of the research communities of science and technology.
引用
收藏
页码:13487 / 13501
页数:15
相关论文
共 106 条
[1]   A polymer electrolyte-based rechargeable lithium/oxygen battery [J].
Abraham, KM ;
Jiang, Z .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (01) :1-5
[2]   Identifying Capacity Limitations in the Li/Oxygen Battery Using Experiments and Modeling [J].
Albertus, Paul ;
Girishkumar, G. ;
McCloskey, Bryan ;
Sanchez-Carrera, Roel S. ;
Kozinsky, Boris ;
Christensen, Jake ;
Luntz, A. C. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2011, 158 (03) :A343-A351
[3]   Some Possible Approaches for Improving the Energy Density of Li-Air Batteries [J].
Andrei, P. ;
Zheng, J. P. ;
Hendrickson, M. ;
Plichta, E. J. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2010, 157 (12) :A1287-A1295
[4]   Catalyst gradient for cathode active layer of proton exchange membrane fuel cell [J].
Antoine, O ;
Bultel, Y ;
Ozil, P ;
Durand, R .
ELECTROCHIMICA ACTA, 2000, 45 (27) :4493-4500
[5]   High-Capacity Lithium-Air Cathodes [J].
Beattie, S. D. ;
Manolescu, D. M. ;
Blair, S. L. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2009, 156 (01) :A44-A47
[6]   Oxygen Reduction Properties of Bifunctional α-Manganese Oxide Electrocatalysts in Aqueous and Organic Electrolytes [J].
Benbow, E. M. ;
Kelly, S. P. ;
Zhao, L. ;
Reutenauer, J. W. ;
Suib, S. L. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (44) :22009-22017
[7]  
Bruce PG, 2012, NAT MATER, V11, P19, DOI [10.1038/nmat3191, 10.1038/NMAT3191]
[8]   Lithium-air and lithium-sulfur batteries [J].
Bruce, Peter G. ;
Hardwick, Laurence J. ;
Abraham, K. M. .
MRS BULLETIN, 2011, 36 (07) :506-512
[9]   Predicting Solvent Stability in Aprotic Electrolyte Li-Air Batteries: Nucleophilic Substitution by the Superoxide Anion Radical (O2•-) [J].
Bryantsev, Vyacheslav S. ;
Giordani, Vincent ;
Walker, Wesley ;
Blanco, Mario ;
Zecevic, Strahinja ;
Sasaki, Kenji ;
Uddin, Jasim ;
Addison, Dan ;
Chase, Gregory V. .
JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 115 (44) :12399-12409
[10]   The role of transition metal interfaces on the electronic transport in lithium-air batteries [J].
Chen, Jingzhe ;
Hummelshoj, Jens S. ;
Thygesen, Kristian S. ;
Myrdal, Jon S. G. ;
Norskov, Jens K. ;
Vegge, Tejs .
CATALYSIS TODAY, 2011, 165 (01) :2-9