Large-scale growth of porous CuInS2 microspheres

被引：48

作者：

Hu, HM

Yang, BJ

Liu, XY

Zhang, R

Qian, YT ^{[1
]}

机构：

[1] Univ Sci & Technol China, Struct Res Lab, Hefei 230026, Anhui, Peoples R China

[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 04期

基金：

中国国家自然科学基金;

关键词：

semiconductor; copper indium disulfide; solvothermal synthesis; porous microspheres;

D O I：

10.1016/j.inoche.2004.02.019

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Uniform CuInS2 porous microspheres were synthesized on a large scale using CuCl2 . 2H(2)O, InCl3 . 4H(2)O and KSCN as starting reagents in ethylene glycol at 200 degreesC for 12 h. XRD result reveals that the obtained products are well crystallized. FESEM observation reveals that the prepared microspheres are composed of sheet-like nanocrystals. The possible formation mechanism was simply discussed. (C) 2004 Elsevier B.V. All rights reserved.

引用

收藏

页码：563 / 565

页数：3

相关论文

共 23 条

[11] Preparation and characterization of CuInS2 nanorods and nanotubes from an elemental solvothermal reaction [J].

Jiang, Y ;

Qu, Y ;

Yuan, SW ;

Xie, B ;

Zhang, SY ;

Qian, YT .

JOURNAL OF MATERIALS RESEARCH, 2001, 16 (10) :2805-2809

[12] Efficient CuInS2 thin-film solar cells prepared by a sequential process [J].

Klaer, J ;

Bruns, J ;

Henninger, R ;

Seimer, K ;

Klenk, R ;

Ellmer, K ;

Bräunig, D .

SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 1998, 13 (12) :1456-1458

[13] Structural and optical properties of sprayed CuInS2 films [J].

Krunks, M ;

Bijakina, O ;

Varema, T ;

Mikli, V ;

Mellikov, E .

THIN SOLID FILMS, 1999, 338 (1-2) :125-130

[14] Synthesis of nanocrystalline CuMS2 (M = In or Ga) through a solvothermal process [J].

Lu, QY ;

Hu, JQ ;

Tang, KB ;

Qian, YT ;

Zhou, GE ;

Liu, XM .

INORGANIC CHEMISTRY, 2000, 39 (07) :1606-+

[15]

Mann S, 2000, ANGEW CHEM INT EDIT, V39, P3393

[16] Epitaxial growth of CuInS2 on sulphur terminated Si(111) [J].

Metzner, H ;

Hahn, T ;

Bremer, JH ;

Conrad, J .

APPLIED PHYSICS LETTERS, 1996, 69 (13) :1900-1902

[17] PREPARATION OF CUINS2 THIN-FILMS BY SINGLE-SOURCE MOCVD PROCESS USING BU2IN(SPR)CU(S2CNPRI2) [J].

NOMURA, R ;

SEKL, Y ;

MATSUDA, H .

JOURNAL OF MATERIALS CHEMISTRY, 1992, 2 (07) :765-766

[18] Polyol-mediated synthesis of porous nanocrystalline CuInS2 foam [J].

Shen, GZ ;

Chen, D ;

Tang, KB ;

Fang, Z ;

Sheng, J ;

Qian, YT .

JOURNAL OF CRYSTAL GROWTH, 2003, 254 (1-2) :75-79

[19] n-CuInS2/polysulfide photoelectrochemical solar cells prepared by spray pyrolysis [J].

Tembhurkar, YD .

BULLETIN OF MATERIALS SCIENCE, 1997, 20 (07) :1011-1014

[20] Hydrothermal synthesis of fine MoS2 crystals from Na2MoO4 and KSCN [J].

Tian, Y ;

He, Y ;

Zhu, YF .

CHEMISTRY LETTERS, 2003, 32 (08) :768-769