A metal-organic framework containing meso-helical chains: Synthesis, characterization and luminescent property

被引：16

作者：

Ashiry, Kother Osman ^{[1
]}

Zhao, Ya-Hui ^{[1
]}

Shao, Kui-Zhan ^{[1
]}

Su, Zhong-Min ^{[1
]}

Fu, Yao-Mei ^{[1
]}

Hao, Xiang-Rong ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Inst Funct Mat Chem, Changchun 130024, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 10期

基金：

中国国家自然科学基金;

关键词：

Bridging ligand; Hydrothermal method; Coordination polymer; X-ray diffraction; Fluorescence;

D O I：

10.1016/j.inoche.2008.06.027

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new metal-organic frameworks (MOFs), [Cd-3(Pmb)(2)(bpdC)(2)] 2H(2)O (1) (pmb = 3,5-bis(4-pyridylmethylenoxyl)benzoate, bpdc = 2,2'-biphenyldicarboxylate), has been synthesized by hydrothermal method and structurally characterized through IR, TG and single-crystal X-ray analysis. The infinite wave-like 1 D metal-oxygen chains made by Cd3N4O12 clusters in 1 bridged by the carboxylate of bpdc ligand, construct a 21) framework in which interesting meso-helical chains are constructed by metal centers and pmb ligands, Solid state luminescent spectrum of I also has been investigated at room temperature. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：1181 / 1183

页数：3

共 40 条

[1]

BARRET RM, 1982, HYDROTHERMAL CHEM ZE

[2] STRUCTURAL CHARACTERIZATION OF THE SOLVATE COMPLEXES OF THE LITHIUM DIORGANOPHOSPHIDES [(LI(ET2O)PPH2)-INFINITY], [(LI(THF)2PPH2)-INFINITY], AND [(LI(THF)P(C6H11)2)-INFINITY] [J].

BARTLETT, RA ;

OLMSTEAD, MM ;

POWER, PP .

INORGANIC CHEMISTRY, 1986, 25 (08) :1243-1247

[3] METAL DERIVATIVES OF MOLECULAR-COMPOUNDS .8. CATENA-POLY[(2,5,8-TRIOXANONANE-O(2),O(5))LITHIUM-METHYLPHOSPHANIDE] - A COMPOUND WITH A MESO-HELIX STRUCTURE [J].

BECKER, G ;

ESCHBACH, B ;

MUNDT, O ;

SEIDLER, N .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1994, 620 (08) :1381-1390

[4] Interconversion of single and double helices formed from synthetic molecular strands [J].

Berl, V ;

Huc, I ;

Khoury, RG ;

Krische, MJ ;

Lehn, JM .

NATURE, 2000, 407 (6805) :720-723

[5] Varying the frameworks of novel silver(I) coordination polymers with thioethers by altering the backbone or terminal groups of ligands [J].

Bu, XH ;

Hou, WF ;

Du, M ;

Chen, W ;

Zhang, RH .

CRYSTAL GROWTH & DESIGN, 2002, 2 (04) :303-307

[6] Layered metal organosulfides:: hydrothermal synthesis, structure and magnetic behaviour of the spin-canted magnet Co(1,2-(O2C)(S)C6H4) [J].

Cave, D ;

Gascon, JM ;

Bond, AD ;

Teat, SJ ;

Wood, PT .

CHEMICAL COMMUNICATIONS, 2002, (10) :1050-1051

[7]

Cheetham AK, 1999, ANGEW CHEM INT EDIT, V38, P3268, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO

[8]

2-U

[9] Multidimensional frameworks assembled from silver(I) coordination polymers containing flexible bis(thioquinolyl) ligands: Role of the intra- and intermolecular aromatic stacking interactions [J].

Chen, CL ;

Su, CY ;

Cai, YP ;

Zhang, HX ;

Xu, AW ;

Kang, BS ;

zur Loye, HC .

INORGANIC CHEMISTRY, 2003, 42 (12) :3738-3750

[10] Interlocked chiral nanotubes assembled from quintuple helices [J].

Cui, Y ;

Lee, SJ ;

Lin, WB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (20) :6014-6015

← 1 2 3 4 →