Microchip capillary electrophoresis-electrochemistry with rigid graphite-epoxy composite detector

被引：12

作者：

Pumera, M ^{[1
]}

Merkoçi, A ^{[1
]}

Alegret, S ^{[1
]}

机构：

[1] Univ Autonoma Barcelona, Dept Quim, Grp Sensors Biosensors, E-08193 Barcelona, Catalonia, Spain

来源：

ELECTROANALYSIS | 2006年 / 18卷 / 02期

关键词：

microchip capillary electrophoresis; electrochemical detection; rigid graphite epoxy composite; glassy carbon electrode; background noise;

D O I：

10.1002/elan.200503382

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A new rigid graphite-epoxy composite electrode for electrochemical detection in microchip electrophoresis is described. The end-column wall-jet detection design relying oil tubular rigid composite working electrode shows favorably low noise level and high signal-to-noise ratio when compared to glassy carbon detector. The performance of rigid graphite-epoxy composite detector was compared to glassy carbon detector using dopamine and catechol its model analytes. The various parameters of the microchip electrophoresis-rigid graphite-epoxy composite detector were optimized.

引用

页码：207 / 210

页数：4

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