First synthesis of sulfines by direct oxidation of xanthates

被引:11
作者
Marriere, E [1 ]
Chevrie, D [1 ]
Metzner, P [1 ]
机构
[1] UNIV CAEN,ISMRA,UNITE MIXTE CNRS,LAB CHIM MOL & THIOORGAN,F-14050 CAEN,FRANCE
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1997年 / 14期
关键词
D O I
10.1039/a703706f
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Sulfines are formed by the reaction of xanthates with m-chloroperoxybenzoic acid; they are spontaneously converted at ambient temperature to thiocarbonates and dithioperoxycarbonates unless kinetic steric protection provided by a substituent makes the sulfine stable.
引用
收藏
页码:2019 / 2020
页数:2
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