Synthesis of nucleic-acid base containing norbornene derivatives as monomers for ring-opening-metathesis-polymerization

被引：44

作者：

Davies, RG

Gibson, VC

Hursthouse, MB

Light, ME

Marshall, EL

North, M ^{[1
]}

Robson, DA

Thompson, I

White, AJP

Williams, DJ

Williams, PJ

机构：

[1] Kings Coll London, Dept Chem, London WC2R 2LS, England

[2] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

[3] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

[4] Univ Wales, Dept Chem, Bangor LL57 2UW, Gwynedd, Wales

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 2001年 / Royal Society of Chemistry卷 / 24期

关键词：

D O I：

10.1039/b107139d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of norbornene derivatives containing nucleic-acid bases (thymine, adenine, cytosine, guanine, or uracil) have been prepared as monomers for ring-opening-metathesis-polymerization (ROMP). Many of the initially prepared monomers had poor solubility but this could be overcome by appropriate choice of a linker between the norbornene and base units. Some of the monomers were successfully polymerised to give homopolymers derived from nucleic-acid bases.

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收藏

页码：3365 / 3381

页数：17

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