Avalanche breakdown in GaTa4Se8 - xTex narrow-gap Mott insulators

被引:102
作者
Guiot, V. [1 ]
Cario, L. [1 ]
Janod, E. [1 ]
Corraze, B. [1 ]
Phuoc, V. Ta [2 ]
Rozenberg, M. [3 ]
Stoliar, P. [3 ]
Cren, T. [4 ]
Roditchev, D. [4 ]
机构
[1] Univ Nantes, CNRS, Inst Mat Jean Rouxel IMN, F-44322 Nantes, France
[2] Univ F Rabelais, CNRS UMR 7347, GREMAN, F-37200 Tours, France
[3] Univ Paris 11, CNRS UMR 8502, Phys Solides Lab, F-91405 Orsay, France
[4] Univ Paris 06, CNRS UMR 7588, Inst Nanosci Paris, F-75005 Paris, France
来源
NATURE COMMUNICATIONS | 2013年 / 4卷
关键词
POSSIBLE SUPERCONDUCTIVITY; BANDGAP SEMICONDUCTORS; ELECTRONIC-PROPERTIES; CRITICAL-BEHAVIOR; TRANSITIONS; MEMORIES; WIDE;
D O I
10.1038/ncomms2735
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Mott transitions induced by strong electric fields are receiving growing interest. Recent theoretical proposals have focused on the Zener dielectric breakdown in Mott insulators. However, experimental studies are still too scarce to conclude about the mechanism. Here we report a study of the dielectric breakdown in the narrow-gap Mott insulators GaTa4Se8 (-) Te-x(x). We find that the I-V characteristics and the magnitude of the threshold electric field (E-th) do not correspond to a Zener breakdown, but rather to an avalanche breakdown. E-th increases as a power law of the Mott-Hubbard gap (E-g), in surprising agreement with the universal law E-th proportional to E-g(2.5) reported for avalanche breakdown in semiconductors. However, the delay time for the avalanche that we observe in Mott insulators is over three orders of magnitude greater than in conventional semiconductors. Our results suggest that the electric field induces local insulator-to-metal Mott transitions that create conductive domains that grow to form filamentary paths across the sample.
引用
收藏
页数:6
相关论文
共 37 条
[1]   Transition from Mott insulator to superconductor in GaNb4Se8 and GaTa4Se8 under high pressure -: art. no. 126403 [J].
Abd-Elmeguid, MM ;
Ni, B ;
Khomskii, DI ;
Pocha, R ;
Johrendt, D ;
Wang, X ;
Syassen, K .
PHYSICAL REVIEW LETTERS, 2004, 93 (12) :126403-1
[2]  
[Anonymous], 1990, Metal-Insulator Transitions
[3]   POSSIBLE HIGH-TC SUPERCONDUCTIVITY IN THE BA-LA-CU-O SYSTEM [J].
BEDNORZ, JG ;
MULLER, KA .
ZEITSCHRIFT FUR PHYSIK B-CONDENSED MATTER, 1986, 64 (02) :189-193
[4]  
BENYAICH H, 1984, J LESS-COMMON MET, V102, P9, DOI 10.1016/0022-5088(84)90384-9
[5]   Electric-Field-Induced Resistive Switching in a Family of Mott Insulators: Towards a New Class of RRAM Memories [J].
Cario, Laurent ;
Vaju, Cristian ;
Corraze, Benoit ;
Guiot, Vincent ;
Janod, Etienne .
ADVANCED MATERIALS, 2010, 22 (45) :5193-+
[6]   Half-Metallic Ferromagnetism and Large Negative Magnetoresistance in the New Lacunar Spinel GaTi3VS8 [J].
Dorolti, Eugen ;
Cario, Laurent ;
Corraze, Benoit ;
Janod, Etienne ;
Vaju, Cristian ;
Koo, Hyun-Joo ;
Kan, Erjun ;
Whangbo, Myung-Hwan .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (16) :5704-5710
[7]   Electric-Field-Assisted Nanostructuring of a Mott Insulator [J].
Dubost, Vincent ;
Cren, Tristan ;
Vaju, Cristian ;
Cario, Laurent ;
Corraze, Benoit ;
Janod, Etienne ;
Debontridder, Francois ;
Roditchev, Dimitri .
ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (17) :2800-2804
[8]   Dielectric Breakdown of Mott Insulators in Dynamical Mean-Field Theory [J].
Eckstein, Martin ;
Oka, Takashi ;
Werner, Philipp .
PHYSICAL REVIEW LETTERS, 2010, 105 (14)
[9]   Control of the Electronic Properties and Resistive Switching in the New Series of Mott Insulators GaTa4Se8-yTey (0 ≤ y ≤ 6.5) [J].
Guiot, V. ;
Janod, E. ;
Corraze, B. ;
Cario, L. .
CHEMISTRY OF MATERIALS, 2011, 23 (10) :2611-2618
[10]   Sound velocity anomaly at the Mott transition:: Application to organic conductors and V2O3 -: art. no. 036402 [J].
Hassan, SR ;
Georges, A ;
Krishnamurthy, HR .
PHYSICAL REVIEW LETTERS, 2005, 94 (03) :1-4