Layer-anion interactions in magnesium aluminum layered double hydroxides intercalated with cobalticyanide and nitroprusside

被引：35

作者：

Boclair, JW

Braterman, PS ^{[1
]}

Brister, BD

Yarberry, F

机构：

[1] Univ N Texas, Dept Chem, Denton, TX 76203 USA

[2] Univ N Texas, Dept Mat Sci, Denton, TX 76203 USA

来源：

CHEMISTRY OF MATERIALS | 1999年 / 11卷 / 08期

关键词：

D O I：

10.1021/cm990148l

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The interactions of cobalticyanide and nitroprusside with magnesium aluminum layered double hydroxide are investigated using oriented infrared spectroscopy together with powder X-ray diffraction. Cobalticyanide is known to intercalate into layered double hydroxides in the same manner as ferrocyanide, with its 3-fold rotational axis perpendicular to the cation sheets. The intercalated cobalticyanide anion shows a small yet observable deviation from local O-h symmetry, causing small differences between its oriented and nonoriented infrared spectra. Nitroprusside is shown to intercalate into 2:1 Mg:Al LDH with decomposition to form intercalated ferrocyanide and nitrosyl groups of an unidentified nature.

引用

收藏

页码：2199 / 2204

页数：6

相关论文

共 35 条

[21] FERROCYANIDE ANION BEARING MG, AL HYDROXIDE [J].

KIKKAWA, S ;

KOIZUMI, M .

MATERIALS RESEARCH BULLETIN, 1982, 17 (02) :191-198

[22] MIXED-VALENCE HYDROXIDES AS BIOORGANIC HOST MINERALS [J].

KUMA, K ;

PAPLAWSKY, W ;

GEDULIN, B ;

ARRHENIUS, G .

ORIGINS OF LIFE AND EVOLUTION OF THE BIOSPHERE, 1989, 19 (06) :573-602

[23] INTERCALATION AND EXCHANGE-REACTIONS OF CLAY-MINERALS AND NON-CLAY LAYER COMPOUNDS [J].

LAGALY, G ;

BENEKE, K .

COLLOID AND POLYMER SCIENCE, 1991, 269 (12) :1198-1211

[24] STEREOSPECIFIC POLYMERIZATION OF PROPYLENE-OXIDE ON THERMALLY ACTIVATED SYNTHETIC HYDROTALCITE [J].

LAYCOCK, DE ;

COLLACOTT, RJ ;

SKELTON, DA ;

TCHIR, MF .

JOURNAL OF CATALYSIS, 1991, 130 (02) :354-358

[25] SYNTHESIS AND CO2 ADSORPTION FEATURES OF A HYDROTALCITE-LIKE COMPOUND OF THE MG2+-AL3+-FE(CN)64- SYSTEM WITH HIGH LAYER-CHARGE DENSITY [J].

MAO, G ;

TSUJI, M ;

TAMAURA, Y .

CLAYS AND CLAY MINERALS, 1993, 41 (06) :731-737

[26] ANION-EXCHANGE PROPERTIES OF HYDROTALCITE-LIKE COMPOUNDS [J].

MIYATA, S .

CLAYS AND CLAY MINERALS, 1983, 31 (04) :305-311

[27] PREPARATION AND PHOSPHATE ION-EXCHANGE PROPERTIES OF A HYDROTALCITE-LIKE COMPOUND [J].

OOKUBO, A ;

OOI, K ;

HAYASHI, H .

LANGMUIR, 1993, 9 (05) :1418-1422

[28] ALDOL CONDENSATION REACTION BETWEEN FORMALDEHYDE AND ACETONE OVER HEAT-TREATED SYNTHETIC HYDROTALCITE AND HYDROTALCITE-LIKE COMPOUNDS [J].

SUZUKI, E ;

ONO, Y .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1988, 61 (03) :1008-1010

[29] PROPERTIES OF HEXACYANOCOBALTATE(III)-EXCHANGED HYDROTALCITE-LIKE MINERALS [J].

SUZUKI, E ;

IDEMURA, S ;

ONO, Y .

CLAYS AND CLAY MINERALS, 1989, 37 (02) :173-178

[30] PHOTOISOMERIZATION OF INDOLINESPIROBENZOPYRAN IN ANIONIC CLAY MATRICES OF LAYERED DOUBLE HYDROXIDES [J].

TAGAYA, H ;

SATO, S ;

KUWAHARA, T ;

KADOKAWA, J ;

MASA, K ;

CHIBA, K .

JOURNAL OF MATERIALS CHEMISTRY, 1994, 4 (12) :1907-1912

← 1 2 3 4 →