Monomerization of a rhenium(V) dimer by ligation

被引：31

作者：

Jacob, J

Lente, G

Guzei, IA

Espenson, JH ^{[1
]}

机构：

[1] Iowa State Univ Sci & Technol, Ames Lab, Ames, IA 50011 USA

[2] Iowa State Univ Sci & Technol, Dept Chem, Ames, IA 50011 USA

来源：

INORGANIC CHEMISTRY | 1999年 / 38卷 / 17期

关键词：

D O I：

10.1021/ic990370s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Coordination of dmso to one of the originally equiva-detected, and the unsymmetrically coordinated adduct was characterized crystallographically. This unsymmetric complex is a key intermediate in the ligand-induced monomerization of the dimer D. A mechanism for monomerization is proposed from kinetics studies.

引用

收藏

页码：3762 / +

页数：3

相关论文

共 12 条

[1] FACILE ABSTRACTION OF SUCCESSIVE OXYGEN-ATOMS FROM PERCHLORATE IONS BY METHYLRHENIUM DIOXIDE [J].

ABUOMAR, MM ;

ESPENSON, JH .

INORGANIC CHEMISTRY, 1995, 34 (25) :6239-&

[2] Oxygen-transfer reactions of methylrhenium oxides [J].

AbuOmar, MM ;

Appelman, EH ;

Espenson, JH .

INORGANIC CHEMISTRY, 1996, 35 (26) :7751-7757

[3] OXYGEN ATOM TRANSFER-REACTIONS OF CATIONIC RHENIUM(III), RHENIUM(V), AND RHENIUM(VII) TRIAZACYCLONONANE COMPLEXES [J].

CONRY, RR ;

MAYER, JM .

INORGANIC CHEMISTRY, 1990, 29 (24) :4862-4867

[4] Atom-transfer reactions catalyzed by methyltrioxorhenium(VII) - mechanisms and applications [J].

Espenson, JH .

CHEMICAL COMMUNICATIONS, 1999, (06) :479-488

[5]

Espenson JH, 1997, ADV CHEM SER, V253, P99

[6] FRAGMENTATION OF, AND OXYGEN-ATOM ABSTRACTION BY, (CP-ASTERISK-RE(O))(2)(MU-O)(2) [J].

GABLE, KP ;

JULIETTE, JJJ ;

GARTMAN, MA .

ORGANOMETALLICS, 1995, 14 (07) :3138-3140

[7]

HORIIKE K, 1977, J BIOCHEM-TOKYO, V81, P179

[8]

HURSTHOUSE MB, 1962, J AM CHEM SOC, V84, P2941

[9] Synthesis, structure, and reactivity of novel dithiolato(oxo)rhenium(V) complexes [J].

Jacob, J ;

Guzei, IA ;

Espenson, JH .

INORGANIC CHEMISTRY, 1999, 38 (06) :1040-+

[10]

ROLLMANN LD, 1972, INORG CHIM ACTA, V6, P137