Molybdenum-doped mesoporous carbon/graphene composites as efficient electrocatalysts for the oxygen reduction reaction

被引：41

作者：

Dong, Youzhen ^{[1
]}

Liu, Mengjia ^{[1
]}

Liu, Yang ^{[1
]}

Wang, Shiwei ^{[1
]}

Li, Jinghong ^{[1
]}

机构：

[1] Tsinghua Univ, Beijing Key Lab Microanalyt Methods & Instrumenta, Dept Chem, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Beijing 100084, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2015年 / 3卷 / 39期

基金：

中国国家自然科学基金;

关键词：

AQUEOUS DISPERSIONS; HYDROGEN EVOLUTION; GRAPHENE; CARBIDE; NANOSTRUCTURES; NANOSHEETS; CATALYSTS; NITRIDE;

D O I：

10.1039/c5ta04624f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

An effective soft template strategy is used for the in situ fabrication of molybdenum-doped mesoporous carbon/graphene composites. As noble-metal-free electrocatalysts for the oxygen reduction reaction in alkaline media, they exhibit excellent catalytic activity through an efficient four-electron-dominant reaction pathway. Observably, compared with commercial Pt/C, they have superior methanol tolerance and long-term stability.

引用

收藏

页码：19969 / 19973

页数：5

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