A Ru-η6-Arene Complex as a C-Based Lewis Acid in the Activation of Hydrogen and Hydrogenation Catalysis

被引：74

作者：

Boone, Michael P. ^{[1
]}

Stephan, Douglas W. ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 23期

基金：

加拿大自然科学与工程研究理事会;

关键词：

AMBIPHILIC LIGANDS; H2; ACTIVATION; METAL; BORANE; PAIRS; CARBENE; RHODIUM; PD; METALLABORATRANES; COORDINATION;

D O I：

10.1021/ja403912n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The PBP ligand (Ph2PC6H4)(2)BPh was used to prepare ((Ph2PC6H4)(2)B(Cl)(eta(6)-Ph)RuCI (1) and subsequently [((Ph2PC6H4)(2)B(eta(6)-Ph))RuCl][B(C6F5)(4)] (2). The latter species exhibited Lewis acidity on the;eta(6)-Ph ring, as reaction with Cy3P gave the donor-acceptor adduct [(Ph2FC6H4)(2)B(eta(5)-C6H5-o-PCy3)RuCl] [B (C6F5)(4)] (3). Steric frustration of this binding was seen with Mes(3)P, and yet the combination of 2 and Mes(3)P reacted with H-2 to give a 2:1 mixture of 5-o and 5-p, two isomers of [(Ph2PC6H4)(2)B(eta(5)-C6H6)RuCl] (5), along with [Mes(3)PH][HB(C6F5)(3)]. Compound 2 behaves as C-. based Lewis acid and thus can also be used for catalytic hydrogenation of aldimines at room temperature via a frustrated Lewis pair mechanism.

引用

页码：8508 / 8511

页数：4

共 47 条

[1] Exploring the Reactivity of Carbon(0)/Borane-Based Frustrated Lewis Pairs [J].

Alcarazo, Manuel ;

Gomez, Catherine ;

Holle, Sigrid ;

Goddard, Richard .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (33) :5788-5791

[2] A Phosphorus/Aluminum-Based Frustrated Lewis Pair as an Ion Pair Receptor: Alkali Metal Hydride Adducts and Phase-Transfer Catalysis [J].

Appelt, Christian ;

Slootweg, J. Chris ;

Lammertsma, Koop ;

Uhl, Werner .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (24) :5911-5914

[3] SYNTHESIS OF SOME (ETA-ARENE)DIHYDRIDORHENIUM CATIONS AND THEIR REACTIONS WITH LIALH4 AND LIALD4 [J].

BAUDRY, D ;

BOYDELL, P ;

EPHRITIKHINE, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (03) :531-535

[4] Rhodium(I) complexes of a PBP ambiphilic ligand:: Evidence for a metal → borane interaction [J].

Bontemps, SB ;

Gornitzka, H ;

Bouhadir, G ;

Miqueu, K ;

Bourissou, D .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (10) :1611-1614

[5] Metallaboratranes derived from a triphosphanyl-borane:: Intrinsic C3 symmetry supported by a Z-type ligand [J].

Bontemps, Sebastien ;

Bouhadir, Ghenwa ;

Gu, Weixing ;

Mercy, Maxime ;

Chen, Chun-Hsing ;

Foxman, Bruce M. ;

Maron, Laurent ;

Ozerov, Oleg V. ;

Bourissou, Didier .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (08) :1481-1484

[6] Ambiphilic diphosphine-borane ligands:: Metal→borane interactions within isoelectronic complexes of rhodium, platinum and palladium [J].

Bontemps, Sebastien ;

Sircoglou, Marie ;

Bouhadir, Ghenwa ;

Puschmann, Horst ;

Howard, Judith A. K. ;

Dyer, Philip W. ;

Miqueu, Karinne ;

Bourissou, Didier .

CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (02) :731-740

[7] On the versatile and unusual coordination behavior of ambiphilic ligands o-R2P(Ph)BR′2 [J].

Bontemps, Sebastien ;

Bouhadir, Ghenwa ;

Miqueu, Karinne ;

Bourissou, Didier .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (37) :12056-12057

[8] Pyridine and phosphine reactions with [CPh3][B(C6F5)4] [J].

Cabrera, Lourdes ;

Welch, Gregory C. ;

Masuda, Jason D. ;

Wei, Pingrong ;

Stephan, Douglas W. .

INORGANICA CHIMICA ACTA, 2006, 359 (09) :3066-3071

[9] Hydrogen and amine activation by a frustrated Lewis pair of a bulky n-heterocyclic carbene and B(C6F5)3 [J].

Chase, Preston A. ;

Stephan, Douglas W. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (39) :7433-7437

[10] Lewis acid-catalyzed hydrogenation:: B(C6F5)3-mediated reduction of imines and nitriles with H2 [J].

Chase, Preston A. ;

Jurca, Titel ;

Stephan, Douglas W. .

CHEMICAL COMMUNICATIONS, 2008, (14) :1701-1703

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