Synthesis and electrochemistry of complexes containing the ferrocenyl-phosphine ligand PPh(CH2CH2-η5-C5H4)2Fe

被引：16

作者：

Adams, JJ

Curnow, OJ

Huttner, G

Smail, SJ

Turnbull, MM

机构：

[1] Univ Canterbury, Dept Chem, Christchurch 1, New Zealand

[2] Univ Heidelberg, Inst Anorgan Chem, D-69120 Heidelberg, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 577卷 / 01期

关键词：

ferrocene; phosphine; heterobimetallics; cyclopentadienyl; Group; 10; molybdenum;

D O I：

10.1016/S0022-328X(98)01032-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of the tethered bis(2-cyclopentadienyl)phenylphosphine compound bis(2-cyclopentadienylethyl)phenylphosp (1) produces moderate yields (40-50%) of the ferrocene complex PPh(CH2CH2-eta5-C5H4)(2)Fe (2). Reaction of 2 with Me,NO in tetrahydrofuran gives the phosphine oxide O=PPh(CH2CH2-eta5-C5H4)(2)Fe (3) whereas treatment with the metal complexes trans-PdCl2(PhCN)(2), cis-PtCl(2()PhCN2), Fe-2(CO)(9), and Mo(CO)(5)(THF) give the corresponding di- or tri-metallic complexes trans -PdCl2[PPh(CH2CH2 eta5 -C5H4)(2)Fe](2) (4), cis-PtCl2[PPh(CH2CH2-(5)(eta)-C5H4)(2)Fe](2) (5), (OC)(4)FePPh(CH2CH2-(5)(eta)-C5H4)(2)Fe (7), and (OC)(5)MoPPh(CH2CH2 eta5-C5H4)(2)Fe (8), respectively, in which 2 is acting as a neutral two-electron-donor phosphine ligand. The electrochemistry of complexes 2, 3, 4, 5 and 7 have been investigated and complexes 3, 4 and 7 have been characterised further by X-ray crystallography. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：44 / 57

页数：14

共 71 条

[61] PHOSPHORUS-BRIDGED AND ARSENIC-BRIDGED [1]FERROCENOPHANES .1. SYNTHESIS AND CHARACTERIZATION
SEYFERTH, D
WITHERS, HP
[J]. ORGANOMETALLICS, 1982, 1 (10) : 1275 - 1282
[62] MODEL ZIEGLER-NATTA ALPHA-OLEFIN POLYMERIZATION CATALYSTS DERIVED FROM [((ETA(5)-C(5)ME(4))SIME(2)(ETA(1)-NCME(3)))(PME(3))SC(MU(2)-H)](2) AND [((ETA(5)-C(5)ME(4))SIME(2)(ETA(1)-NCME(3)))SC(MU(2)-CH2CH2CH3)](2) - SYNTHESIS, STRUCTURES, AND KINETIC AND EQUILIBRIUM INVESTIGATIONS OF THE CATALYTICALLY ACTIVE SPECIES IN SOLUTION
SHAPIRO, PJ
COTTER, WD
SCHAEFER, WP
LABINGER, JA
BERCAW, JE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (11) : 4623 - 4640
[63] SHELDRICK G, SHELXL 93 PROGRAM CR
[64] PHASE ANNEALING IN SHELX-90 - DIRECT METHODS FOR LARGER STRUCTURES
SHELDRICK, GM
[J]. ACTA CRYSTALLOGRAPHICA SECTION A, 1990, 46 : 467 - 473
[65] NEW HETERODIFUNCTIONAL LIGANDS FOR ORGANOTRANSITON-METAL CHEMISTRY - PH2P(CH2)NC5ME4H, PH2P(CH2)2C5ME4H
SZYMONIAK, J
BESANCON, J
DORMOND, A
MOISE, C
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (05) : 1429 - 1432
[66] 2,6-BIS(METHYLENECYCLOPENTADIENYL)-PYRIDINE-ZIRCONOCENE AND -HAFNOCENE DICHLORIDE - FORMATION AND CRYSTAL-STRUCTURE OF [C5H3N-2,6-(CH2-C5H4)(2)ZR(CL)(OH2)][ZRCL6]
THIELE, KH
SCHLIESSBURG, C
NEUMULLER, B
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (06): : 1106 - 1110
[67] Tongi A., 1995, FERROCENES HOMOGENEO
[68] THE SYNTHESIS AND X-RAY STRUCTURES OF YTTERBOCENE(II) COMPLEXES CONTAINING PENDANT PYRIDYL GROUPS, [YB(CPX)2] (CPX=ETA(5)-C5H3(R)[CME2(CH2)NC5H4N-2]-1,3 - R=H OR SIME3 AND N=0 OR 1)
VANDENHENDE, JR
HITCHCOCK, PB
LAPPERT, MF
NILE, TA
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 472 (1-2) : 79 - 85
[69] Coordination of ethene and propene to a cationic d(0) vanadium center
Witte, PT
Meetsma, A
Hessen, B
Budzelaar, PHM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (43) : 10561 - 10562
[70] PREPARATION OF 1,1'-BIS[(DIPHENYLPHOSPHINO)METHYL]FERROCENE AND ITS TRANSITION-METAL COMPLEXES
YAMAMOTO, Y
TANASE, T
MORI, I
NAKAMURA, Y
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (21): : 3191 - 3192

← 1 2 3 4 5 6 7 8 →