A study toward understanding the role of a phosphorus stereogenic center in (5S)-1,3-diaza-2-phospha-2-oxo-3-phenylbicyclo(3.3.0)octane derivatives as catalysts in the borane-mediated asymmetric reduction of prochiral ketones

被引：20

作者：

Basavaiah, D ^{[1
]}

Chandrashekar, V ^{[1
]}

Das, U ^{[1
]}

Reddy, GJ ^{[1
]}

机构：

[1] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India

来源：

TETRAHEDRON-ASYMMETRY | 2005年 / 16卷 / 24期

关键词：

D O I：

10.1016/j.tetasy.2005.10.038

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Representative diastereomeric pairs of chiral catalysts, containing the (5S)-1,3-diaza-2-phospha-2-oxo-3-phenylbicyclo(3.3.0)octane moiety, with different stereochemistry at the phosphorus stereogenic center, have been synthesized and their stereoselection in the borane-mediated asymmetric reduction of representative prochiral ketones has been described. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：3955 / 3962

页数：8

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