Preparation of stable aqueous dispersion of graphene nanosheets and their electrochemical capacitive properties

被引:37
作者
Jin, Yuhong [1 ]
Jia, Mengqiu [1 ]
Zhang, Mei [1 ]
Wen, Qianqian [1 ]
机构
[1] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Key Lab Beijing City Preparat & Proc Novel Polyme, Beijing 100029, Peoples R China
关键词
Graphite; Graphene; Graphene oxide; Supercapacitor; EXFOLIATED GRAPHITE OXIDE; SUPERCAPACITOR; SHEETS; FILMS;
D O I
10.1016/j.apsusc.2012.10.130
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Using potassium hydroxide as the reduction agent, a stable aqueous dispersion of graphene nanosheets was successfully prepared and characterized for its structural and electrochemical properties for supercapacitor application. The structure and morphology of the as-prepared material were investigated by Fourier transform infrared spectra, X-ray diffraction pattern and high resolution transmission electron microscopy, respectively. The electrochemical supercapacitive properties of as-prepared material were evaluated using cyclic voltammetry, galvanostatic charge-discharge methods and electrochemical impedance spectroscopy. The as-prepared material showed maximum specific capacitance of (200 F g(-1)) in 6.0 M aqueous KOH electrolyte at scan rate 5 mV s(-1). For comparison, we add the data of traditional chemical reduction agent-hydrazine. (C) 2012 Elsevier B. V. All rights reserved.
引用
收藏
页码:787 / 793
页数:7
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