Intramolecular Frustrated Lewis Pairs: Formation and Chemical Features

被引：70

作者：

Kehr, Gerald ^{[1
]}

Schwendemann, Sina ^{[1
]}

Erker, Gerhard ^{[1
]}

机构：

[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

来源：

FRUSTRATED LEWIS PAIRS I: UNCOVERING AND UNDERSTANDING | 2013年 / 332卷

关键词：

FLP addition reactions; Small molecule activation; Synergistic reactions; Vicinal and geminal frustrated Lewis pairs; FREE CATALYTIC-HYDROGENATION; HETEROLYTIC DIHYDROGEN ACTIVATION; H-2; ACTIVATION; ALTERNATIVE LIGANDS; PHOSPHINE-BORANES; BOND ACTIVATION; B-N; REACTIVITY; BORON; 1,1-CARBOBORATION;

D O I：

10.1007/128_2012_373

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Intramolecular vicinal and geminal frustrated Lewis pairs (FLPs) featuring bulky substituents at phosphorus or nitrogen and strongly electron-withdrawing bulky pentafluorophenyl substituents at boron undergo a variety of addition and/or activation reactions with small molecules. A number of examples of such reactions are presented and discussed, among them the FLP activation of dihydrogen to give zwitterionic phosphonium (or ammonium)/hydridoborate zwitterions. Intramolecular FLPs also add to organic carbonyl compounds (including carbon dioxide), to alkenes and alkynes (including conjugated dienes, diynes or enynes), to heterocumulenes, to azides, and to nitric oxide.

引用

页码：45 / 83

页数：39

共 126 条

[1]

[Anonymous], 2010, ANGEW CHEM-GER EDIT

[2] A Phosphorus/Aluminum-Based Frustrated Lewis Pair as an Ion Pair Receptor: Alkali Metal Hydride Adducts and Phase-Transfer Catalysis [J].

Appelt, Christian ;

Slootweg, J. Chris ;

Lammertsma, Koop ;

Uhl, Werner .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (24) :5911-5914

[3] REACTION OF 1,2-BORYLPHOSPHINOETHENE WITH PHENYL ISOCYANATE AND THE STRUCTURE OF THE REACTION-PRODUCTS [J].

ARBUZOV, BA ;

NIKONOV, GN ;

BALUEVA, AS ;

KAMALOV, RM ;

PUDOVIK, MA ;

SHAGIDULLIN, RR ;

PLYAMOVATYI, AK ;

KHADIULLIN, RS .

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1991, 40 (10) :2099-2102

[4] Non-Metal-Mediated Homogeneous Hydrogenation of CO2 to CH3OH [J].

Ashley, Andrew E. ;

Thompson, Amber L. ;

O'Hare, Dermot .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (52) :9839-9843

[5] Structure and Dynamic Features of an Intramolecular Frustrated Lewis Pair [J].

Axenov, Kirill V. ;

Moemming, Cornelia M. ;

Kehr, Gerald ;

Froehlich, Roland ;

Erker, Gerhard .

CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (47) :14069-14073

[6] Functional Group Chemistry at the Group 4 Bent Metallocene Frameworks: Formation and "Metal-Free" Catalytic Hydrogenation of Bis(imino-Cp)zirconium Complexes [J].

Axenov, Kirill V. ;

Kehr, Gerald ;

Froehlich, Roland ;

Erker, Gerhard .

ORGANOMETALLICS, 2009, 28 (17) :5148-5158

[7] Catalytic Hydrogenation of Sensitive Organometallic Compounds by Antagonistic N/B Lewis Pair Catalyst Systems [J].

Axenov, Kirill V. ;

Kehr, Gerald ;

Froehlich, Roland ;

Erker, Gerhard .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (10) :3454-+

[8] SYNTHESIS OF 3,4,6-BORATAOXAPHOSPHONIACYCLOHEXENES [J].

BALUEVA, AS ;

ERASTOV, OA .

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1988, 37 (01) :151-153

[9] SYNTHESIS AND PROPERTIES OF 1-DIPHENYLBORYL-2-DIPHENYLPHOSPHINO-1,2-DIPHENYLETHENE [J].

BALUEVA, AS ;

NIKONOV, GN .

RUSSIAN CHEMICAL BULLETIN, 1993, 42 (02) :341-343

[10] SYNTHESIS AND SOME PROPERTIES OF ORTHO-BORYLPHENYLPHOSPHINE [J].

BALUEVA, AS ;

NIKONOV, GN ;

ARBUZOV, BA ;

MUSIN, RZ ;

EFREMOV, YY .

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1991, 40 (10) :2103-2105

← 1 2 3 4 5 6 7 8 9 10 →