Template-Directed Assembly of Zeolite-like Metal-Organic Frameworks (ZMOFs): A usf-ZMOF with an Unprecedented Zeolite Topology

被引:266
作者
Liu, Yunling [1 ,2 ]
Kravtsov, Victor Ch. [1 ,3 ]
Eddaoudi, Mohamed [1 ]
机构
[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA
[2] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
[3] Moldavian Acad Sci, Inst Appl Phys, MD-2028 Kishinev, Moldova
基金
美国国家科学基金会;
关键词
indium; metal-organic frameworks; porous materials; template synthesis; zeolite analogues;
D O I
10.1002/anie.200802680
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Better off med: The assembly of eight-coordinate indium molecular building blocks (MBBs) and 4,5-imidazoledicarboxylate (Himdc) ligands in the presence of a structure-directing agent results in the formation a novel 4-connected zeolite-like metal-organic framework (ZMOF) with an unprecedented zeolite topology (med topology, see picture; In green, C gray, N blue, O red; the framework topology of usf-ZMOF is shown in green tetrahedra). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:8446 / 8449
页数:4
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