"Frustrated Lewis pair" hydrogenations

被引：245

作者：

Stephan, Douglas W. ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2012年 / 10卷 / 30期

关键词：

FREE CATALYTIC-HYDROGENATION; HETEROLYTIC DIHYDROGEN ACTIVATION; H-2; ACTIVATION; REACTIVITY; IMINES; PHOSPHINES; MECHANISM; BORANE; DERIVATIVES; ENAMINES;

D O I：

10.1039/c2ob25339a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This perspective article discusses developments of metal-free hydrogenation catalysts derived from "frustrated Lewis pair" (FLP) systems. The range of catalysts uncovered and the applications to reductions of imines, aziridines, enamines, silyl enol ethers, diimines, metallocene derivatives and nitrogen-based heterocycles are described. In addition, FLP aromatic reduction of aniline derivatives to the cyclohexylamine analogs is discussed. The potential applications of these metal-free reductions are considered.

引用

页码：5740 / 5746

页数：7

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