Liquid-crystalline fullerodendrimers which display columnar phases

被引:47
作者
Lenoble, J
Maringa, N
Campidelli, S
Donnio, B
Guillon, D
Deschenaux, R
机构
[1] Univ Neuchatel, Inst Chim, CH-2009 Neuchatel, Switzerland
[2] ULP, CNRS, UMR 7504, Inst Phys & Chim Mat Strasbourg,Grp Mat Organ, F-67034 Strasbourg 2, France
关键词
D O I
10.1021/ol0603920
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The title compounds were synthesized by applying the 1,3-dipolar cycloaddition reaction of aldehyde-based poly(benzyl ether) dendrimers and sarcosine (N-methylglycine) to [60]fullerene (C-60). The dendritic building blocks used to functionalize C-60 displayed cubic and hexagonal columnar phases. The fullerene derivatives showed rectangular columnar phases of c2mm symmetry.
引用
收藏
页码:1851 / 1854
页数:4
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