Liquid-crystalline fullerodendrimers which display columnar phases

被引:47
作者
Lenoble, J
Maringa, N
Campidelli, S
Donnio, B
Guillon, D
Deschenaux, R
机构
[1] Univ Neuchatel, Inst Chim, CH-2009 Neuchatel, Switzerland
[2] ULP, CNRS, UMR 7504, Inst Phys & Chim Mat Strasbourg,Grp Mat Organ, F-67034 Strasbourg 2, France
关键词
D O I
10.1021/ol0603920
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The title compounds were synthesized by applying the 1,3-dipolar cycloaddition reaction of aldehyde-based poly(benzyl ether) dendrimers and sarcosine (N-methylglycine) to [60]fullerene (C-60). The dendritic building blocks used to functionalize C-60 displayed cubic and hexagonal columnar phases. The fullerene derivatives showed rectangular columnar phases of c2mm symmetry.
引用
收藏
页码:1851 / 1854
页数:4
相关论文
共 49 条
[31]   Photovoltaic action of conjugated polymer/fullerene bulk heterojunction solar cells using novel PPE-PPV copolymers [J].
Hoppe, H ;
Egbe, DAM ;
Mühlbacher, D ;
Sariciftci, NS .
JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (23) :3462-3467
[32]   Porphyrin- and fullerene-based molecular photovoltaic devices [J].
Imahori, H ;
Fukuzumi, S .
ADVANCED FUNCTIONAL MATERIALS, 2004, 14 (06) :525-536
[33]   Self-organization of supramolecular complex composed of rigid dendritic porphyrin and fullerene [J].
Kimura, M ;
Saito, Y ;
Ohta, K ;
Hanabusa, K ;
Shirai, H ;
Kobayashi, N .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (19) :5274-5275
[34]   Stacking of molecules possessing a fullerene apex and a cup-shaped cavity connected by a silicon connection [J].
Matsuo, Y ;
Muramatsu, A ;
Hamasaki, R ;
Mizoshita, N ;
Kato, T ;
Nakamura, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (02) :432-433
[35]   Methanofullerene molecular scaffolding: Towards C-60-substituted poly(triacetylenes) and expanded radialenes, preparation of a C-60-C-70 hybrid derivative, and a novel macrocyclization reaction [J].
Nierengarten, JF ;
Herrmann, A ;
Tykwinski, RR ;
Ruttimann, M ;
Diederich, F ;
Boudon, C ;
Gisselbrecht, JP ;
Gross, M .
HELVETICA CHIMICA ACTA, 1997, 80 (01) :293-316
[36]   Amphiphilic diblock dendrimers: Synthesis and incorporation in Langmuir and Langmuir-Blodgett films [J].
Nierengarten, JF ;
Eckert, JF ;
Rio, Y ;
Carreon, MD ;
Gallani, JL ;
Guillon, D .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (40) :9743-9748
[37]   Programming the internal structure and stability of helical pores self-assembled from dendritic dipeptides via the protective groups of the peptide [J].
Percec, V ;
Dulcey, AE ;
Peterca, M ;
Ilies, M ;
Sienkowska, MJ ;
Heiney, PA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (50) :17902-17909
[38]   Self-assembly of semifluorinated janus-dendritic benzamides into bilayered pyramidal columns [J].
Percec, V ;
Imam, MR ;
Bera, TK ;
Balagurusamy, VSK ;
Peterca, M ;
Heiney, PA .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (30) :4739-4745
[39]   Synthesis and structural analysis of two constitutional isomeric libraries of AB2-based monodendrons and supramolecular dendrimers [J].
Percec, V ;
Cho, WD ;
Ungar, G ;
Yeardley, DJP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (07) :1302-1315
[40]   Visualizable cylindrical macromolecules with controlled stiffness from backbones containing libraries of self-assembling dendritic side groups [J].
Percec, V ;
Ahn, CH ;
Cho, WD ;
Jamieson, AM ;
Kim, J ;
Leman, T ;
Schmidt, M ;
Gerle, M ;
Möller, M ;
Prokhorova, SA ;
Sheiko, SS ;
Cheng, SZD ;
Zhang, A ;
Ungar, G ;
Yeardley, DJP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (34) :8619-8631