Liquid-crystalline fullerodendrimers which display columnar phases

被引:47
作者
Lenoble, J
Maringa, N
Campidelli, S
Donnio, B
Guillon, D
Deschenaux, R
机构
[1] Univ Neuchatel, Inst Chim, CH-2009 Neuchatel, Switzerland
[2] ULP, CNRS, UMR 7504, Inst Phys & Chim Mat Strasbourg,Grp Mat Organ, F-67034 Strasbourg 2, France
关键词
D O I
10.1021/ol0603920
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The title compounds were synthesized by applying the 1,3-dipolar cycloaddition reaction of aldehyde-based poly(benzyl ether) dendrimers and sarcosine (N-methylglycine) to [60]fullerene (C-60). The dendritic building blocks used to functionalize C-60 displayed cubic and hexagonal columnar phases. The fullerene derivatives showed rectangular columnar phases of c2mm symmetry.
引用
收藏
页码:1851 / 1854
页数:4
相关论文
共 49 条
[11]   Functional polypedes - chiral nematic fullerenes [J].
Campidelli, S ;
Eng, C ;
Saez, IM ;
Goodby, JW ;
Deschenaux, R .
CHEMICAL COMMUNICATIONS, 2003, (13) :1520-1521
[12]   Efficient cyclopropanation of C-60 starting from malonates [J].
Camps, X ;
Hirsch, A .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1997, (11) :1595-1596
[13]   Stable Langmuir and Langmuir-Blodgett films of fullerene-glycodendron conjugates [J].
Cardullo, F ;
Diederich, F ;
Echegoyen, L ;
Habicher, T ;
Jayaraman, N ;
Leblanc, RM ;
Stoddart, JF ;
Wang, SP .
LANGMUIR, 1998, 14 (08) :1955-1959
[14]   A liquid-crystalline hexa-adduct of [60]fullerene [J].
Chuard, T ;
Deschenaux, R ;
Hirsch, A ;
Schönberger, H .
CHEMICAL COMMUNICATIONS, 1999, (20) :2103-2104
[15]   Design, mesomorphic properties, and supramolecular organization of [60]fullerene-containing thermotropic liquid crystals [J].
Chuard, T ;
Deschenaux, R .
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (07) :1944-1951
[16]   First fullerene[60]-containing thermotropic liquid crystal - Preliminary communication [J].
Chuard, T ;
Deschenaux, R .
HELVETICA CHIMICA ACTA, 1996, 79 (03) :736-741
[17]   Fullerene-containing liquid-crystalline dendrimers [J].
Dardel, B ;
Guillon, D ;
Heinrich, B ;
Deschenaux, R .
JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (11) :2814-2831
[18]   Synthesis, characterization, and mesomorphic properties of a mixed [60]fullerene-ferrocene liquid-crystalline dendrimer [J].
Dardel, B ;
Deschenaux, R ;
Even, M ;
Serrano, E .
MACROMOLECULES, 1999, 32 (16) :5193-5198
[19]   Electronic communication through π-conjugated wires in covalently linked porphyrin/C60 ensembles [J].
de la Torre, G ;
Giacalone, F ;
Segura, JL ;
Martín, N ;
Guldi, DM .
CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (04) :1267-1280
[20]   Fullerene-oligophenylenevinylene hybrids: Synthesis, electronic properties, and incorporation in photovoltaic devices [J].
Eckert, JF ;
Nicoud, JF ;
Nierengarten, JF ;
Liu, SG ;
Echegoyen, L ;
Barigelletti, F ;
Armaroli, N ;
Ouali, L ;
Krasnikov, V ;
Hadziioannou, G .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (31) :7467-7479