Iron-catalyzed annulation reaction of arylindium reagents and alkynes to produce substituted naphthalenes

被引：38

作者：

Adak, Laksmikanta ^{[1
]}

Yoshikai, Naohiko ^{[1
]}

机构：

[1] Nanyang Technol Univ, Div Chem & Biol Chem, Sch Phys & Math Sci, Singapore 637371, Singapore

来源：

TETRAHEDRON | 2012年 / 68卷 / 26期

基金：

新加坡国家研究基金会;

关键词：

Iron catalysis; Organoindium reagent; Alkyne; C-H bond functionalization; Naphthalene; H BOND ACTIVATION; C-H; INTERNAL ALKYNES; ARYL IODIDES; COUPLING REACTIONS; METAL; INDIUM; ARYLMAGNESIATION; CARBOMETALATION; PHENYLAZOLES;

D O I：

10.1016/j.tet.2012.04.004

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report here an iron-bisphosphine complex-catalyzed annulation reaction of an arylindium reagent and two alkyne molecules that affords a substituted naphthalene derivative in moderate to good yield. The reaction represents a new example of iron-catalyzed C-C bond forming reactions via C-H bond functionalization. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：5167 / 5171

页数：5

共 57 条

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