Artificial Protection Film on Lithium Metal Anode toward Long-Cycle-Life Lithium-Oxygen Batteries

被引：439

作者：

Liu, Qing-Chao ^{[1
]}

Xu, Ji-Jing ^{[2
]}

Yuan, Shuang ^{[1
]}

Chang, Zhi-Wen ^{[2
,3
]}

Xu, Dan ^{[2
]}

Yin, Yan-Bin ^{[1
]}

Li, Lin ^{[1
]}

Zhong, Hai-Xia ^{[2
]}

Jiang, Yin-Shan ^{[1
]}

Yan, Jun-Min ^{[1
]}

Zhang, Xin-Bo ^{[2
]}

机构：

[1] Jilin Univ, Sch Mat Sci & Engn, Changchun 130012, Peoples R China

[2] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China

[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

ADVANCED MATERIALS | 2015年 / 27卷 / 35期

基金：

中国国家自然科学基金;

关键词：

anodes; artificial protection films; Li-oxygen batteries; lithium metal; long cycle life; LI-O-2; BATTERY; DISCHARGE PRODUCTS; CATHODE CATALYSTS; AIR BATTERIES; PERFORMANCE; ELECTROLYTE; NANOCRYSTALS; LI2O2; MORPHOLOGY; REDUCTION;

D O I：

10.1002/adma.201501490

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An artificial while very stable solid electrolyte interphase film is formed on lithium metal using an electrochemical strategy. When this protected Li anode is first used in a Li-O2 battery, the film formed on the anode can effectively suppress the parasitic reactions on the Li anode/electrolyte interface and significantly enhance the cycling stability of the Li-O2 battery. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5241 / 5247

页数：7

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