Effective Fixation of CO2 by Iridium-Catalyzed Hydrosilylation

被引：121

作者：

Lalrempuia, Ralte ^{[1
]}

Iglesias, Manuel ^{[1
]}

Polo, Victor ^{[2
]}

Sanz Miguel, Pablo J. ^{[1
]}

Fernandez-Alvarez, Francisco J. ^{[1
]}

Perez-Torrente, Jesus J. ^{[1
]}

Oro, Luis A. ^{[1
]}

机构：

[1] Univ Zaragoza, CSIC, Dept Quim Inorgan, ISQCH, E-50009 Zaragoza, Spain

[2] Univ Zaragoza, Dept Quim Fis, E-50009 Zaragoza, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 51期

关键词：

carbon dioxide fixation; hydrosilylation; iridium; NSiN ligands; silyl formate; CARBON-DIOXIDE; REDUCTION; COMPLEXES; HYDROGENATION; TRANSFORMATION; HYDROSILANES; ACTIVATION; METHANE; SILANES;

D O I：

10.1002/anie.201206165

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

CO2 as feedstock: An air- and moisture-stable iridium(III) catalyst effectively promotes the hydrosilylation of CO2. This reaction leads to silyl formate in a highly selective manner and proceeds efficiently under mild conditions, most likely by an outer-sphere mechanism, as suggested by theoretical calculations. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12824 / 12827

页数：4

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