Metal-Organic Frameworks as Biomimetic Catalysts

被引：241

作者：

Gu, Zhi-Yuan ^{[1
]}

Park, Jihye ^{[1
]}

Raiff, Aaron ^{[1
]}

Wei, Zhangwen ^{[1
]}

Zhou, Hong-Cai ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

CHEMCATCHEM | 2014年 / 6卷 / 01期

关键词：

artificial enzyme; biomimetic synthesis; heterogeneous catalysis; mesoporous materials; metal-organic frameworks; microporous materials; HETEROGENEOUS CATALYSTS; ENERGY-TRANSFER; PORPHYRIN; SERIES; MOFS; ADSORPTION; MIGRATION; OXIDATION; CHEMISTRY; STRATEGY;

D O I：

10.1002/cctc.201300493

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this Minireview, we have summarized the recent progress of biomimetic catalysis in the field of metal-organic frameworks (MOFs) with a focus on the implantation of biomimetic active sites into a stable MOF. In addition, the potential of creating highly selective catalytic pockets and diffusion-favored hierarchical structures in MOFs has also been explored. Furthermore, we have highlighted the achievements of MOF catalysts in the applications as mimics of peroxidase, cytochromes P450, hemoglobin, and photosynthetic systems.

引用

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页码：67 / 75

页数：9

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