Synthesis and structure of a hydrido (hydrosilylene) ruthenium complex and its reactions with Nitriles

被引：91

作者：

Ochiai, Mitsityoshi ^{[1
]}

Hashimoto, Hisako ^{[1
]}

Tobita, Hiromi ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 43期

关键词：

D O I：

10.1002/anie.200703154

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Ring around the Ru=Si: Abstraction of a pyridine ligand with BPh3 was used to synthesize the silylene complex 1 (see scheme), which reacts with nitriles at room temperature to give silylisocyanide complex 3 by C-C bond activation. The structure of key intermediate 2 with an η2-Si-H agostic interaction is given along with mechanisms for the formation of 2 and 3. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8192 / 8194

页数：3

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