Degradation of triterpenic compounds from olive-pressing residues.: Synthesis of trans-decalin type chiral synthons

被引：11

作者：

García-Granados, A ^{[1
]}

López, PE ^{[1
]}

Melguizo, E ^{[1
]}

Parra, A ^{[1
]}

Simeó, Y ^{[1
]}

机构：

[1] Univ Granada, Fac Ciencias, Dept Quim Organ, E-18071 Granada, Spain

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 35期

关键词：

D O I：

10.1016/S0040-4039(03)01634-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Three seco-Gring triterpenic compounds were obtained from oleanolic or maslinic acids from olive-mill solid wastes by photochemical and chemical reactions. From these oleantriene compounds, different remarkable sesquiterpene and nor-sesquiterpene fragments such as 3beta-hydroxydrimenol (13) and epoxydecalone (16) were achieved through oxidative cleavages of the double bonds in the opened Gring. (C) 2003 Published by Elsevier Ltd.

引用

页码：6673 / 6677

页数：5

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