Coordination polymers of flexible tetracarboxylic acids with metal ions. II. Supramolecular assemblies of 5,5′-methylene- and 5,5′-(ethane-1,2-diyl)-bis(oxy)diisophthalic acid ligands with d-transition metals

被引：53

作者：

Karmakar, Anirban ^{[1
]}

Goldberg, Israel ^{[1
]}

机构：

[1] Tel Aviv Univ, Sackler Fac Exact Sci, Sch Chem, IL-69978 Tel Aviv, Israel

来源：

CRYSTENGCOMM | 2011年 / 13卷 / 01期

基金：

以色列科学基金会;

关键词：

SECONDARY-BUILDING UNITS; ORGANIC FRAMEWORK MATERIALS; CLOSED-SHELL INTERACTIONS; HIGH H-2 ADSORPTION; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURE; HYDROGEN STORAGE; POSTSYNTHETIC MODIFICATION; CATENATION ISOMERISM; RETICULAR SYNTHESIS;

D O I：

10.1039/c0ce00268b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This report evaluates the coordination patterns of the 5,5'-methylene-bis(oxy)diisophthalic acid and 5,5'-(ethane-1,2-diyl)-bis(oxy)diisophthalic acid ligands, bearing flexible spacers between the two isophthalic acid fragments, with a series of d-metal ions. Thirteen new binary and ternary (with additional bipyridyl components) hybrid organic-inorganic coordination-driven assemblies were investigated in detail by X-ray crystallography. In most cases they exhibit polymeric architectures of three-dimensional connectivity, the formation of which is facilitated by the conformational flexibility of the ligands.

引用

页码：350 / 366

页数：17

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