Solubilities of 4-phenyltoluene, phenylboric acid, biphenyl, and iodobenzene in carbon dioxide from measurements of the relative permittivity

被引:20
作者
Leeke, G [1 ]
Santos, R
Al-Duri, B
Seville, J
Smith, C
Holmes, AB
机构
[1] Univ Birmingham, Ctr Chem & Formulat Engn, Birmingham B15 2TT, W Midlands, England
[2] Univ Cambridge, Dept Chem, Melville Lab Polymer Synth, Cambridge CB2 3RA, England
关键词
D O I
10.1021/je050075o
中图分类号
O414.1 [热力学];
学科分类号
摘要
Solubility data were obtained for the first time for phenylboric acid, iodobenzene, and biphenyl in carbon dioxide at (353 and 383) K and between pressures of (100 to 300) bar. Data were obtained using a method that used the relative permittivity of the binary mixture. The technique was verified by comparison of solubility data for 4-phenyltoluene that had been determined previously by ourselves using a cloud point technique. The relative permittivity for CO2 was also determined at (353 and 383) K between pressures of (100 to 300) bar.
引用
收藏
页码:1370 / 1374
页数:5
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