Preparation and properties of disilane and disiloxane unit-fused poly(diphenylamine)

被引：20

作者：

Hayashi, H

Nakao, H

Onozawa, SY

Adachi, A

Hayashi, T

Okita, K

机构：

[1] Nagoya Municipal Ind Res Inst, Atsuta Ku, Nagoya, Aichi 4560058, Japan

[2] Natl Food Res Inst, Tsukuba, Ibaraki 3058642, Japan

[3] Natl Inst AIST, Tsukuba, Ibaraki 3058565, Japan

[4] Japan Chem Innovat Inst, Chiyoda Ku, Tokyo 1010051, Japan

来源：

POLYMER JOURNAL | 2003年 / 35卷 / 09期

关键词：

diphenylamine; dibenzazepine; cyclic voltammetry; X-ray crystal structure;

D O I：

10.1295/polymj.35.704

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Disilane unit-fused poly (diphenylamine) (poly(10, 11-dihydro-10,11-disila-5,10, 10,11,11-pentamethyl-5H-dibenz[b,f]azepine-2,8-diyl), PDSiAzep) were prepared and properties of these compounds were studied. Oxidation of PDSiAzep led to related disiloxane-fused poly(diphenylamine) (poly(5,7-disila-6-oxa-5,5,7,7,12-pentamethyl-5,6,7,12-tetrahydrodibenz[b,g]azocine-3,9-diyl) PSiO). These polymers have new heterocyclic unit. Not only UV and Cyclic voltammetry (CV) measurements but also X-ray crystallography of the related dibromide suggested that the structure of the bridging unit affected pi-conjugation through the N atom. The highest conductivities of electrochemically doped PDSiAzep and PSiO were 2.0 x 10(-4) and 1.3 x 10(-2), respectively. Turn-on bias voltage of a double layer electroluminescent device comprising PDSiAzep was higher than that of PSiO. These electrical properties were depended on effective a-conjugation through the N atom.

引用

页码：704 / 710

页数：7

共 17 条

[1] Multilayer electroluminescent device using organosilicon polymer as hole transport layer [J].