Systematic structural coordination chemistry of p-tert-butyltetrathiacalix[4]arene:: 1.: Group 1 elements and congeners

被引:106
作者
Bilyk, A
Hall, AK
Harrowfield, JM [1 ]
Hosseini, MW
Skelton, BW
White, AH
机构
[1] Univ Western Australia, Special Res Ctr Adv Mineral & Mat Proc, Nedlands, WA 6907, Australia
[2] Univ Western Australia, Dept Chem, Nedlands, WA 6907, Australia
[3] Univ Strasbourg 1, Inst Le Bel, Chim Coordinat Organ Lab, F-67000 Strasbourg, France
关键词
D O I
10.1021/ic001008c
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Determinations of the crystal structures of complexes of the alkali metal ions with, in the case of Li, the dianion and, in the cases Na-Cs, the monoanion of p-tert-butyltetrathiacalix[4]arene have shown that both the sulfur atoms which form part of the macrocyclic ring, as well as the pendent phenolic/phenoxide oxygen donor atoms, are involved in coordination to these metals. Although the Li and Na complex structures are similar to these of the corresponding complexes of p-tert-butylcalix[4]arene, there is no similarity in the structures of the Cs complexes, with the present structure showing no evidence of polyhapto Cs+-pi interactions. Instead, the complex crystallizes as a ligand-bridged (S-, O-donor) aggregate of three Cs ions, solvent molecules, and four calixarenes, somewhat like the Rb complex, though here four Rb ions are present, and higher in aggregation than the K+ complex, where two K+ ions are sandwiched between two calixarene moieties. The triethylammonium complex of the thiacalixarene monoanion, though formally analogous in that it involves a monocation. has a simpler structure than any of the alkali metal derivatives, based formally on proton coordination (H-bonding). However, interestingly, it can be isolated in both solvated (dmf, dmso) and unsolvated forms, as indeed can the "free", p-tert-butyltetrathiacalix[4]arene ligand itself.
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页码:672 / 686
页数:15
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共 73 条
  • [41] ON THE UNUSUAL CONFORMATION OF CALIX[4]ARENE WHICH APPEARS IN THE TRICARBONYLCHROMIUM COMPLEXES
    IKI, H
    KIKUCHI, T
    TSUZUKI, H
    SHINKAI, S
    [J]. CHEMISTRY LETTERS, 1993, (10) : 1735 - 1738
  • [42] X-RAY CRYSTALLOGRAPHIC STUDIES OF TRICARBONYLCHROMIUM COMPLEXES OF CALIX[4]ARENE CONFORMERS - ON AN UNUSUAL CONFORMATION WHICH APPEARS IN CONE CONFORMERS
    IKI, H
    KIKUCHI, T
    TSUZUKI, H
    SHINKAI, S
    [J]. JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, 1994, 19 (1-4): : 227 - 236
  • [43] Selective synthesis of three conformational isomers of tetrakis[(ethoxycarbonyl)methoxy]thiacalix[4]arene and their complexation properties towards alkali metal ions
    Iki, N
    Narumi, F
    Fujimoto, T
    Morohashi, N
    Miyano, S
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1998, (12): : 2745 - 2750
  • [44] Coordination of epithio groups of p-tert-butylthiacalix[4]arene in a Zn2+ complex studied by X-ray crystallography
    Iki, N
    Morohashi, N
    Kabuto, C
    Miyano, S
    [J]. CHEMISTRY LETTERS, 1999, (03) : 219 - 220
  • [45] High complexation ability of thiacalixarene with transition metal ions. The effects of replacing methylene bridges of tetra(p-t-butyl)calix[4]arenetetrol by epithio groups
    Iki, N
    Morohashi, N
    Narumi, F
    Miyano, S
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1998, 71 (07) : 1597 - 1603
  • [46] Selective oxidation of thiacalix[4]arenes to the sulfinyl- and sulfonylcalix[4]arenes and their coordination ability to metal ions
    Iki, N
    Kumagai, H
    Morohashi, N
    Ejima, K
    Hasegawa, M
    Miyanari, S
    Miyano, S
    [J]. TETRAHEDRON LETTERS, 1998, 39 (41) : 7559 - 7562
  • [47] CATION-TRANSPORT FROM MULTIPLE ALKALI CATION MIXTURES USING A LIQUID MEMBRANE SYSTEM CONTAINING A SERIES OF CALIXARENE CARRIERS
    IZATT, SR
    HAWKINS, RT
    CHRISTENSEN, JJ
    IZATT, RM
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (01) : 63 - 66
  • [48] Remarkable thallium(I) selectivity for ion sensors based on π-coordination of calix[4]arene neutral carriers
    Kimura, K
    Tatsumi, K
    Yokoyama, M
    Ouchi, M
    Mocerino, M
    [J]. ANALYTICAL COMMUNICATIONS, 1999, 36 (06): : 229 - 230
  • [49] Facile synthesis of p-tert-butylthiacalix[4]arene by the reaction of p-tert-butylphenol with elemental sulfur in the presence of a base
    Kumagai, H
    Hasegawa, M
    Miyanari, S
    Sugawa, Y
    Sato, Y
    Hori, T
    Ueda, S
    Kamiyama, H
    Miyano, S
    [J]. TETRAHEDRON LETTERS, 1997, 38 (22) : 3971 - 3972
  • [50] LAUTERBACH M, 1996, PHYSICAL SUPRAMOLECU, P1