A Metal-Organic Framework with a Covalently Prefabricated Porous Organic Linker

被引:86
作者
Swamy, Shashikala I.
Bacsa, John
Jones, James T. A.
Stylianou, Kyriakos C.
Steiner, Alexander
Ritchie, Lyndsey K.
Hasell, Tom
Gould, Jamie A.
Laybourn, Andrea
Khimyak, Yaroslav Z.
Adams, Dave J.
Rosseinsky, Matthew J. [1 ]
Cooper, Andrew I.
机构
[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England
基金
英国工程与自然科学研究理事会;
关键词
DESIGN; CO2; ADSORPTION; COMPLEXES; FIXATION;
D O I
10.1021/ja104083y
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report here the synthesis of a metal organic framework comprising an organic cage linker with covalently prefabricated, intrinsic porosity. The network can be compared to a porous rock salt structure where the pores are partially filled by charge-balancing cations.
引用
收藏
页码:12773 / 12775
页数:3
相关论文
共 24 条
[1]   Selective adsorption and separation of xylene isomers and ethylbenzene with the microporous vanadium(IV) terephthalate MIL-47 [J].
Alaerts, Luc ;
Kirschhock, Christine E. A. ;
Maes, Michael ;
van der Veen, Monique A. ;
Finsy, Vincent ;
Depla, Anouschka ;
Martens, Johan A. ;
Baron, Gino V. ;
Jacobs, Pierre A. ;
Denayer, Joeri E. M. ;
De Vos, Dirk E. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (23) :4293-4297
[2]  
ASHLEIGH JF, 2001, J AM CHEM SOC, V123, P10001
[3]   High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture [J].
Banerjee, Rahul ;
Phan, Anh ;
Wang, Bo ;
Knobler, Carolyn ;
Furukawa, Hiroyasu ;
O'Keeffe, Michael ;
Yaghi, Omar M. .
SCIENCE, 2008, 319 (5865) :939-943
[4]   Design, chirality, and flexibility in nanoporous molecule-based materials [J].
Bradshaw, D ;
Claridge, JB ;
Cussen, EJ ;
Prior, TJ ;
Rosseinsky, MJ .
ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :273-282
[5]   Porous, crystalline, covalent organic frameworks [J].
Côté, AP ;
Benin, AI ;
Ockwig, NW ;
O'Keeffe, M ;
Matzger, AJ ;
Yaghi, OM .
SCIENCE, 2005, 310 (5751) :1166-1170
[6]   Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].
Eddaoudi, M ;
Kim, J ;
Rosi, N ;
Vodak, D ;
Wachter, J ;
O'Keeffe, M ;
Yaghi, OM .
SCIENCE, 2002, 295 (5554) :469-472
[7]   Designed synthesis of 3D covalent organic frameworks [J].
El-Kaderi, Hani M. ;
Hunt, Joseph R. ;
Mendoza-Cortes, Jose L. ;
Cote, Adrien P. ;
Taylor, Robert E. ;
O'Keeffe, Michael ;
Yaghi, Omar M. .
SCIENCE, 2007, 316 (5822) :268-272
[8]   Metal-Organic Frameworks: Opportunities for Catalysis [J].
Farrusseng, David ;
Aguado, Sonia ;
Pinel, Catherine .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (41) :7502-7513
[9]   Hybrid porous solids:: past, present, future [J].
Ferey, Gerard .
CHEMICAL SOCIETY REVIEWS, 2008, 37 (01) :191-214
[10]   Metal-organic frameworks as efficient materials for drug delivery [J].
Horcajada, Patricia ;
Serre, Christian ;
Vallet-Regi, Maria ;
Sebban, Muriel ;
Taulelle, Francis ;
Ferey, Gerard .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (36) :5974-5978