Trifluoromethylation of Carbonyl Compounds

被引：19

作者：

Boechat, N. ^{[1
]}

Bastos, M. M. ^{[1
]}

机构：

[1] Fundacao Oswaldo Cruz, BR-21041250 Rio De Janeiro, Brazil

来源：

CURRENT ORGANIC SYNTHESIS | 2010年 / 7卷 / 05期

关键词：

Carbonyl compounds; nucleophilic reagents; sulfur tetrafluoride; TDAE; trifluoromethylation; trifluoromethyltrimethylsilane; NUCLEOPHILIC TRIFLUOROMETHYLATION; ENANTIOSELECTIVE TRIFLUOROMETHYLATION; CATALYZED TRIFLUOROMETHYLATION; ELECTROORGANIC CHEMISTRY; STABLE REAGENTS; ALDEHYDES; KETONES; TRIFLUOROMETHYLTRIMETHYLSILANE; PERFLUOROALKYLATION; BASE;

D O I：

10.2174/157017910792246081

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This paper reviews the recent findings on trifluoromethylation of carbonyl compounds. Emphasis was given to the description of the trifluoromethylating agents, their activation mode, their reaction with carbonyl compounds, as well as applications in organic synthesis.

引用

页码：403 / 413

页数：11

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