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Effect of microwave annealing temperatures on lead zirconate titanate thin films
被引:34
作者:
Bhaskar, Ankam
Chang, H. Y.
Chang, T. H.
Cheng, S. Y.
机构:
[1] Natl Tsing Hua Univ, Dept Phys, Hsinchu 30013, Taiwan
[2] Natl Taiwan Ocean Univ, Dept Marine Engn, Chilung 20224, Taiwan
[3] Ind Technol Res Inst, Mat & Chem Res Labs, Hsinchu 31060, Taiwan
关键词:
D O I:
10.1088/0957-4484/18/39/395704
中图分类号:
TB3 [工程材料学];
学科分类号:
0805 ;
080502 ;
摘要:
Lead zirconate titanate (Pb-1.1( Zr0.52Ti0.48)O-3) thin films of thickness 260 nm on Pt/Ti/SiO2/Si substrates were densified by 2.45 GHz microwave annealing. The PZT thin films were annealed at various annealing temperatures from 400 to 700 degrees C for 30 min. X-ray diffraction showed that the pyrochlore phase was transformed to the perovskite phase at 450 degrees C and the film was fully crystallized. The secondary ( again pyrochlore) phase was observed in the PZT thin films, which were annealed above 550 degrees C. The surface morphologies were changed above 550 degrees C of the PZT thin films due to the secondary phase. Higher dielectric constant (epsilon(r)) and lower dielectric loss coercive field (E-c) were achieved for the 450 degrees C film than for the other annealed films.
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