Daphnezomines P, Q, R and S, new alkaloids from Daphniphyllum humile

被引：55

作者：

Morita, H ^{[1
]}

Takatsu, H ^{[1
]}

Kobayashi, J ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Pharmaceut Sci, Sapporo, Hokkaido 0600812, Japan

来源：

TETRAHEDRON | 2003年 / 59卷 / 20期

关键词：

Daphniphyllum alkaloids; iridoid glycoside; NMR; MS/MS;

D O I：

10.1016/S0040-4020(03)00542-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Four new alkaloids, daphnezomines P-S (1-4), have been isolated from the fruits of Daphniphyllum humile, and the structures and the stereochemistry were elucidated on the basis of spectroscopic data including 2D NMR and MSIMS spectra, and chemical correlations. Daphnezomines P (1) and Q (2) were the first Daphniphyllum alkaloids with an iridoid glycoside moiety. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：3575 / 3579

页数：5

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